Urban Form (UF), as a synthesis of urban functions and socioeconomic elements, is closely associated with Anthropogenic Carbon Emissions (ACE) and has important implications for low-carbon urban planning. As a key national economic strategy region, the Yangtze River Economic Belt (YREB) exhibits pronounced heterogeneity in urban development, highlighting the urgent need to elucidate the interaction mechanisms between UF and ACE to support carbon reduction strategies. This study employs nighttime light data and carbon emission records from 2002 to 2022 in the YREB. By integrating Support Vector Regression (SVR), Random Forest (RF), and Gradient Boosting Decision Tree (GBDT), we developed a neural network ensemble model (RSG-Net) to analyze the impacts and driving mechanisms of UF on ACE. The results indicate the following: (1) Over the past two decades, total ACE in the YREB increased by 196%, displaying a three-phase trajectory of rapid growth, deceleration, and rebound. (2) The RSG-Net model achieved superior predictive performance, with an R² of 0.93, an RMSE of 1.96 × 10⁶ t, an RPD of 3.69, and a PBIAS of 4.53%. (3) Based on Pearson correlation analysis and SHAP (Shapley Additive Explanations) feature importance, beyond economic and demographic indicators, the most influential UF indicators are ranked as Number of Urban Patches (NP), Normalized Difference Vegetation Index (NDVI), and Construction Land Concentration (CLC). These findings demonstrate that the RSG-Net model can not only predict ACE but also identify key UF factors and explain their interrelationships, thereby providing technical support for the formulation of urban carbon reduction strategies.