The preparation of chemically reduced graphene oxide (rGO) and the optimization of epoxy resins’ properties using micro or nanofillers are now common practices. rGO nanoparticles (60 nm) based on an epoxy resin polymer were prepared at the concentrations of 0, 1, 2, 3, 4, and 5% weight percentage with fixed 6-mm thicknesses. The dielectric properties of the composites were measured by the reflection/transmission technique in connection with a vector network analyser (VNA) at a frequency range of 8–12 GHz. The microwave absorption and shielding effectiveness properties were calculated by using the reflection S₁₁ and transmission S₂₁ results. The microstructure and morphology of the polymer and the rGO/cured epoxy composites were studied by field emission scanning electron microscopy (FE-SEM), Fourier-transform infrared (FT-IR) spectroscopy, and the X-ray Diffraction (X-RD) technique for characterizing crystalline materials. The dielectric and other properties of the rGO/cured epoxy composites were investigated based on the filler load and frequency. It was found that the applied frequency and the filler concentrations affected the dielectric properties of the rGO/cured epoxy composites. The results showed that the introduction of rGO particles to the composites increased their dielectric properties smoothly. The study of the dependence on frequency of both the dielectric constant ε′ and the dielectric loss ε″ showed a decrease in both quantities with increasing frequency, indicating a normal behaviour of the dielectrics. Cole–Cole plots were drawn with ε′ and ε″. A theoretical simulation in terms of the Cole–Cole dispersion law indicates that the Debye relaxation processes in the rGO/cured epoxy composites are improved due to the presence of the rGO filler. Moreover, with the addition of rGO as a filler into the Epoxy matrix, it now exhibits promise as a lightweight material for microwave absorption as well as an effective electromagnetic interference (EMI) shielding material.

Recycled hematite (α-Fe₂O₃) nanoparticles with enhanced complex permittivity properties have been incorporated as a filler in a polycaprolactone (PCL) matrix reinforced with oil palm empty fruit bunch (OPEFB) fiber for microwave absorption applications. The complex permittivity values were improved by reducing the particle sizes to the nano scale via high-energy ball milling for 12 h. A total of 5–20 wt.% recycled α-Fe₂O₃/OPEFB/PCL nanocomposites were examined for their complex permittivity and microwave absorption properties via the open ended coaxial (OEC) technique and the transmission/reflection line measurement using a microstrip connected to a two-port vector network analyzer. The microstructural analysis of the samples included X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and Fourier transform infrared spectroscopy (FTIR). At 1 GHz, the real (ε′) and imaginary (ε″) parts of complex permittivity of recycled α-Fe₂O₃ particles, respectively, increased from 7.88 to 12.75 and 0.14 to 0.40 when the particle size was reduced from 1.73 μm to 16.2 nm. A minimum reflection loss of −24.2 dB was achieved by the 20 wt.% nanocomposite at 2.4 GHz. Recycled α-Fe₂O₃ nanoparticles are effective fillers for microwave absorbing polymer-based composites in 1–4 GHz range applications.

Low dielectric loss and low-cost recycled borosilicate (BRS) glass-reinforced polytetrafluoroethylene (PTFE) composites were fabricated for microwave substrate applications. The composites were prepared through a dry powder processing technique by dispersing different micron sizes (25 µm, 45 µm, 63 µm, 90 µm, and 106 µm) of the recycled BRS filler in the PTFE matrix. The effect of the filler sizes on the composites’ thermal, mechanical, and dielectric properties was studied. The dielectric properties of the composites were characterised in the frequency range of 1–12 GHz using an open-ended coaxial probe (OCP) connected to a vector network analyser (VNA). XRD patterns confirmed the phase formation of PTFE and recycled BRS glass. The scanning electron microscope also showed good filler dispersion at larger filler particle sizes. In addition, the composites’ coefficient of thermal expansion and tensile strength decreased from 12.93 MPa and 64.86 ppm/°C to 7.12 MPa and 55.77 ppm/°C when the filler size is reduced from 106 μm to 25 μm. However, moisture absorption and density of the composites increased from 0.01% and 2.17 g/cm³ to 0.04% and 2.21 g/cm³. The decrement in filler size from 106 $\mathsf{\mu }$m to 25 $\mathsf{\mu }$m also increased the mean dielectric constant and loss tangent of the composites from 2.07 and 0.0010 to 2.18 and 0.0011, respectively, while it reduced the mean signal transmission speed from 2.088 × 10⁸ m/s to 2.031 × 10⁸ m/s. The presented results showed that PTFE/recycled BRS composite exhibited comparable characteristics with commercial high-frequency laminates.

The purpose of this study was to synthesize high-quality recycled α-Fe₂O₃ to improve its complex permittivity properties by reducing the particles to nanosize through high energy ball milling. Complex permittivity and permeability characterizations of the particles were performed using open-ended coaxial and rectangular waveguide techniques and a vector network analyzer. The attenuation characteristics of the particles were analyzed with finite element method (FEM) simulations of the transmission coefficients and electric field distributions using microstrip model geometry. All measurements and simulations were conducted in the 8–12 GHz range. The average nanoparticle sizes obtained after 8, 10 and 12 h of milling were 21.5, 18, and 16.2 nm, respectively, from an initial particle size of 1.73 µm. The real and imaginary parts of permittivity increased with reduced particle size and reached maximum values of 12.111 and 0.467 at 8 GHz, from initial values of 7.617 and 0.175, respectively, when the particle sizes were reduced from 1.73 µm to 16.2 nm. Complex permeability increased with reduced particle size while the enhanced absorption properties exhibited by the nanoparticles in the simulations confirmed their ability to attenuate microwaves in the X-band frequency range.

The purpose of this study was to improve the dielectric, magnetic, and thermal properties of polytetrafluoroethylene (PTFE) composites using recycled Fe₂O₃ (rFe₂O₃) nanofiller. Hematite (Fe₂O₃) was recycled from mill scale waste and the particle size was reduced to 11.3 nm after 6 h of high-energy ball milling. Different compositions (5–25 wt %) of rFe₂O₃ nanoparticles were incorporated as a filler in the PTFE matrix through a hydraulic pressing and sintering method in order to fabricate rFe₂O₃–PTFE nanocomposites. The microstructure properties of rFe₂O₃ nanoparticles and the nanocomposites were characterized through X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and high-resolution transmission electron microscopy (HRTEM). The thermal expansion coefficients (CTEs) of the PTFE matrix and nanocomposites were determined using a dilatometer apparatus. The complex permittivity and permeability were measured using rectangular waveguide connected to vector network analyzer (VNA) in the frequency range 8.2–12.4 GHz. The CTE of PTFE matrix decreased from $65.28\times {10}^{-6}/°\mathrm{C}$ to $39.84\times {10}^{-6}/°\mathrm{C}$ when the filler loading increased to 25 wt %. The real (ε′) and imaginary (ε″) parts of permittivity increased with the rFe₂O₃ loading and reached maximum values of 3.1 and 0.23 at 8 GHz when the filler loading was increased from 5 to 25 wt %. A maximum complex permeability of $\left(1.1-j0.07\right)$ was also achieved by 25 wt % nanocomposite at 10 GHz.

Epoxy resin (ER) composites reinforced with micro‐sized oil palm empty fruit bunch (OPEFB) were fabricated to improve the biodegradability of electromagnetic interference connector gasket. The dielectric properties, transmission coefficient | S ₂₁ |, reflection coefficient | S ₁₁ |, reflection loss, power loss and shielding effectiveness were studied at a frequency range of 8–12 GHz. OPEFB–ER composites were prepared by varying the percentages of OPEFB (0, 5, 10, 15, 20, 25, 30 and 40%) at room temperature (25°C ±2). Dielectric constant ( ɛ ′), loss factor ( ɛ ″), reflection and transmission coefficients of the composites were measured using rectangular waveguide connected to vector network analyser. In addition, ɛ ′ and ɛ ″ were used in finite element method technique to obtain | S ₁₁ | and | S ₂₁ |. The results showed that the dielectric properties increased but | S ₁₁ | and | S ₂₁ | decreased with increasing OPEFB percentage in the composites. The shielding effectiveness, power loss and reflection loss increased with increasing OPEFB percentage in the composites. The simulated and measured results of | S ₁₁ | and | S ₂₁ | were in good agreement.