In this work, three low-carbon bainitic steels, with different Mo contents, were designed to investigate the effects of Mo addition on microstructure and mechanical properties. Two-step cooling, i.e., initial accelerated cooling and subsequent slow cooling, was used to obtain the desired bainite microstructure. The results show that the product of strength and elongation first increases and then shows no significant change with increasing Mo. Compared with Mo-free steel, bainite in the Mo-containing steel tends to have a lath-like morphology due to a decrease in the bainitic transformation temperature. More martensite transformation occurs with the increasing Mo, resulting in greater hardness of the steel. Both the strength and elongation of the steel can be enhanced by Mo addition; however, the elongation may decrease with a further increase in Mo. From a practical viewpoint, the content of Mo could be ~0.14 wt. % for the composition design of low-carbon bainitic steels in the present work. To be noted, an optimal scheme may need to consider other situations such as the role of sheet thickness, toughness behavior and so on, which could require changes in the chemistry. Nevertheless, these results provide a reference for the composition design and processing method of low-carbon bainitic steels.

Three low‐carbon bainitic steels were designed to investigate the effects of Cr and Al addition on bainitic transformation, microstructures, and properties by metallographic method and dilatometry. The results show that compared with the base steel without Cr and Al addition, only Cr addition is effective for improving the strength of low‐carbon bainitic steel by increasing the amount of bainite. However, compared with the base steel, combined addition of Cr and Al has no significant effect on bainitic transformation and properties. In Cr‐bearing steel, Al addition accelerates initial bainitic transformation, but meanwhile reduces the final amount of bainitic transformation due to the formation of a high‐temperature transformation product such as ferrite. Consequently, the composite strengthening effect of Cr and Al addition is not effective compared with individual addition of Cr in low‐carbon bainitic steels. Therefore, in contrast to high‐carbon steels, bainitic transformation in Cr‐bearing low‐carbon bainitic steels can be finished in a short time, and Al should not be added because Al addition would result in lower mechanical properties.

Two low carbon carbide-free bainitic steels (with and without Cr addition) were designed, and each steel was treated by two kinds of heat treatment procedure (austempering and continuous cooling). The effects of Cr addition on bainitic transformation, microstructure, and properties of low carbon bainitic steels were investigated by dilatometry, metallography, X-ray diffraction, and a tensile test. The results show that Cr addition hinders the isothermal bainitic transformation, and this effect is more significant at higher transformation temperatures. In addition, Cr addition increases the tensile strength and elongation simultaneously for austempering treatment at a lower temperature. However, when the austempering temperature is higher, the strength increases and the elongation obviously decreases by Cr addition, resulting in the decrease in the product of tensile strength and elongation. Meanwhile, the austempering temperature should be lower in Cr-added steel than that in Cr-free steel in order to obtain better comprehensive properties. Moreover, for the continuous cooling treatment in the present study, the product of tensile strength and elongation significantly decreases with Cr addition due to more amounts of martensite.

In order to study the effect of the Si content on the morphology, amount, and distribution of fayalite (Fe₂SiO₄), three low-carbon steels with different Si contents were selected, and reheating tests were conducted in an industrial furnace in a hot strip plant. The results show that Si distributes in two forms—first, Fe₂SiO₄, in the innermost layer of the oxide scale, and, second, granular SiO₂, dispersively distributed in the matrix near the scale. In addition, Fe₂SiO₄ appears in a net-like form in the innermost layer of the oxide scale close to the iron matrix when the Si content is 1.21 wt. %. However, no obvious net-like Fe₂SiO₄ is observed when the Si content is less than 0.25 wt. %. Moreover, the inhibition effect of the solid Fe₂SiO₄ on the oxidation reaction plays a more important role than the promotion effect of the liquid Fe₂SiO₄ during the entire oxidation reaction. Therefore, the total thickness of the scale decreases with the increase in Si content.

An advanced bainite rail with high strength–toughness combination was produced in a steel mill and the effects of tempering on the microstructure and properties of the bainite rail steel were investigated by optical microscopy, transmission electron microscopy, electron back-scattering diffraction and X-ray diffraction. Results indicate that the tensile strength, elongation and impact toughness were about 1470 MPa, 14.5% and 83 J/cm², respectively, after tempering at 400 °C for 200 min. Therefore, a high-strength bainite rail steel with good toughness was developed. In addition, the amount of retained austenite (RA) decreased due to bainite transformation after low-temperature tempering (300 °C) and RA almost disappeared after high-temperature tempering (500 °C). Moreover, as the tempering temperature increased, the tensile strength of the rail head first decreased due to the decreased dislocation density and carbon content in bainite ferrite and the coarseness of bainite ferrite, and then increased because of carbide precipitation at high-temperature tempering. Furthermore, RA played a significant role in the toughness of bainite rail. The elongation and toughness of the rail obviously decreased after tempering at 500 °C for 200 min because of the disappearance of RA and appearance of carbides.

The oxidation behavior of silicon-containing steel was studied by applying segmented heating routes similar to the atmosphere and heating process in an industrial reheating furnace. The oxidation tests were carried out on a simultaneous thermal analyzer at heating temperatures of 1150 °C–1300 °C. The morphologies of Fe₂SiO₄ were observed by SEM, and the penetration depths of the Fe₂SiO₄ layer at different oxidation temperatures were determined by using the Image-Pro Plus 6.0 software. The results show that at heating temperatures ≥1235 °C, the oxidation rate and total oxidation mass gain have no relation with the heating temperature; the mass gain versus time follows a linear law after about 1164 °C (lower than the eutectic temperature of fayalite). In addition, the oxidation rate first decreases slowly and then drops from 1190 °C to 1210 °C during the isothermal holding stage. With the increase in temperature, the oxidation rate and mass gain also increase gradually; the relationship between the mass gain and time is close to a parabolic law. Moreover, at a heating temperature of 1150 °C, the oxidation rate decreases rapidly during the isothermal holding stage, and the mass gain versus time follows a parabolic law.