Ti/TiBCN composite coatings were prepared on a 7075 aluminum alloy surface by laser cladding. The relation between the main processing parameters (i.e., laser power, scanning speed, and powder feeding rate) and the geometrical characteristics (i.e., height, width, penetration depth, dilution and wetting angle) of single clad tracks is studied by linear regression analysis. The microstructure, micro-hardness and electrochemical corrosion were investigated by scanning electron microscopy, a Vickers micro-hardness machine, and a standard three-electrode cell, respectively. The results showed that all geometrical track characteristics are observed with high values of the correlation coefficient (R > 0.95). In addition, the average hardness value (750 HV_0.2) was obtained of the Ti/TiBCN composite coating, and polarization curves indicated that the composite coatings were harder to corrode than the substrate.

TiC/316L stainless steel composites were prepared by selective laser melting. The adhesion work, interface energy and electronic structure of the TiC/γ-Fe interfaces in TiC/316L stainless steel composites were studied to investigate the heterogeneous nucleation potential of γ-Fe grains on TiC particles by using the first principle. The degree mismatch between TiC (001) and γ-Fe (001) interface was lowest. There are four TiC (001)/γ-Fe (001) interface models with different stacking sequences (on-site and bridge-site) and different atomic arrangement sequences (C centre and Ti centre). The results show that the Fe-on-Ti centre interface had the largest work of adhesion (3.87 J/m²) and lower interfacial energy (0.04 J/m²), it was more stable, and the interfacial energy of the model was lower than that of γ-Fe/Fe melt (0.24 J/m²). Strong Fe-C covalent bonds and Fe-Ti metallic bonds were formed near the interface, which increased the interfacial strength, indicating that TiC had strong heterogeneous nucleation potency for γ-Fe.

This paper investigated the effect of silicon phase morphology and size on microstructure, mechanical properties, and corrosion resistance of the AlSi10Mg alloys fabricated by selective laser melting (SLM). Using different heat treatment conditions for SLM-fabricated alloys, the microstructure characteristics and mechanical properties are analyzed. The corrosion behavior analysis is also performed using potentiodynamic polarization, electrochemical and immersion tests. Results show that the AlSi10Mg alloy directly fabricated by SLM has a continuous eutectic silicon network, which has a small driving force for corrosion and facilitates the deposition of corrosion products and generates a dense protective film. On the contrary, the formation of large isolated and uniformly distributed silicon particles produces a greater corrosion driving force after heat treatment, which makes most of the corrosion products transfer to the solution. The corrosion resistance of AlSi10Mg alloy directly fabricated by SLM is better than that of the alloys with heat treatment. Moreover, the heat treatment reduces the hardness of AlSi10Mg alloys due to the decrease in the solid solution strengthening effect.

Al2O3 ceramic-lined steel pipe was produced by self-propagating high-temperature synthesis centrifugal thermite process (SHS C-T process) from Fe2O3 and Al as the raw materials. The composition, phase separation and microstructures were investigated. The result showed the ceramic lined pipe is composed of the three main layers of various compositions, which were subsequently determined to be Fe layer, the transition layer and the ceramic layer. Fe layer is composed of austenite and ferrite, the transition layer consisted of Al2O3 ceramic and Fe, the ceramic layer consisted of the dendritic-shaped Al2O3 and the spinel-shaped structured FeAl2O4.

In this paper, TiBCN-ceramic-reinforced Ti-based coating was fabricated on a Ti6Al4V substrate surface by laser cladding. The correlations between the main processing parameters and the geometrical characteristics of single clad tracks were predicted by linear regression analysis. On this basis, the microstructure, microhardness, corrosion resistance, and wear resistance of the coating and the substrate were investigated. The results showed that the clad height, clad width, clad depth, and dilution rate depended mainly on the laser power, the powder feeding rate, and the scanning speed. TiBCN-ceramic-reinforced Ti-based coating was mainly composed of directional dendritic TiBCN phases, equiaxed TiN phases, needle-like Al₃Ti phases, and Ti phases. The microhardness gradually increased from the bottom to the top of the coating. The highest microhardness of coating was 1025 HV, which was three times higher than that of the Ti6Al4V substrate (350 HV). Furthermore, the coating exhibited excellent corrosion resistance and wear resistance. The corrosion potential (E_corr) reached −1.258 V, and the corrosion density (I_corr) was 4.035 × 10⁻⁵ A/cm², which was one order lower than that of the Ti6Al4V substrate (1.172 × 10⁻⁴ A/cm²). The coating wear mass loss was 4.35 mg, which was about two-third of the wear mass loss of the Ti6Al4V substrate (6.71 mg).