High-entropy alloys (HEAs) with good ductility and high strength are usually prepared by a combination of forging and heat-treatment processes. In comparison, the as-cast HEAs typically do not reach strengths similar to those of HEAs produced by the forging and heat-treatment processes. Here we report a novel equiatomic-ratio CoCrCuMnNi HEA prepared by vacuum arc melting. We observe that this HEA has excellent mechanical properties, i.e., a yield strength of 458 MPa, and an ultimate tensile strength of 742 MPa with an elongation of 40%. Many nanometer precipitates (5–50 nm in size) and domains (5–10 nm in size) are found in the inter-dendrite and dendrite zones of the produced HEA, which is the key factor for its excellent mechanical properties. The enthalpy of mixing between Cu and Mn, Cr, Co, or Ni is higher than those of mixing between any two of Cr, Co, Ni and Mn, which leads to the separation of Cu from the CoCrCuMnNi HEA. Furthermore, we reveal the nanoscale-precipitate-phase-forming mechanism in the proposed HEA.

Via controlling the carbon content, a multiscale reinforcing phase, especially a nano-reinforcement phase in the α₂ lamellar, is formed. This not only improves the microstructure but also improves the room and high temperature mechanical properties.

Intermetallic alloys with high melting point can mostly serve as promising high-temperature structural materials, but their intrinsic brittleness limits their further application. Herein, we developed a strategy to realize high strength and high plasticity simultaneously in Cr-rich γ-TiAl-based intermetallic alloys via introducing high-density deformation nanotwins. Non-equilibrium continuous casting followed by annealing in the (α + γ) phase region generated numerous Shockley partial dislocations and stacking faults as well as a number of α₂ nanoparticles in the γ-TiAl phase. The substantial Shockley partial dislocations and stacking faults acting as effective heterogeneous nucleation sites favored the generation of high-density nanotwins in the as-annealed alloys during deformation, especially within the γ lamellae. This strategy can also be applied to other brittle alloys with a favorable twinning deformation mechanism and paves the way for the development of high-strength and high-ductility materials.