Emerging regulations in the context of sustainability have placed renewed attention on construction protocols, including consideration of end-of-life, waste reduction and a shift to bioplastics. However, much research is required on the integration and compatibility of bioplastic materials and their performance concerning construction industry standards. Parallel to the material perspective, increased efforts are placed on additive manufacturing (AM) processes in architectural design and their potential contribution to sustainability through experimentation with new materials, enhanced performance prototyping and reduction in material use. Within this context, the following paper develops a framework towards large-scale additive manufacturing examining bioplastic compounds for architectural components with acoustic performance. A design workflow outlines the component geometry and micro-structuring for both scattering and absorption. It explores the ability to expand on the acoustic behaviour of the chosen materials through printing techniques such as pull printing, fiber printing and dynamic structure printing, within a robotic FDM setup utilizing non-planar tool path design. The robotic workflow developed, outlines a material-informed calibration of bioplastic compounds, their predicted acoustic compatibility to the construction industry, and highlights the potential of such AM workflows to align with current sustainability goals.