Supply chain operations reference (SCOR) is a combined benchmarking, business process reengineering, and best practices, and it also references a model that is intended to be an industry standard. SCOR model is one of the best models to describe supply chain activities in operations management for research and practice alike. There are radical changes in the structure of supply chains as well as developing technology in today’s information age. The purpose of this paper is to extend the SCOR model with new metrics related to Industry 4.0 and digitalization to understand and evaluate the performance of supply chains. New metrics added to the SCOR model and a novel SCOR 4.0 model is proposed. The novel performance evaluation model is structured as a three-level hierarchical structure to evaluate the supply chain. This problem is handled as a multi-criteria decision-making problem. This study uses the hybrid Best worst method and Pythagorean fuzzy AHP method to determine the weights of metrics. SCOR model is adapted to performance evaluation of the supply chain in the globalizing world. The most important metrics on the supply chain performances are determined and classified. Level 1 metrics are evaluated by Best worst method and their inner levels are evaluated by the Pythagorean fuzzy AHP method and the importance weights of each level 2 and level 3 metrics are obtained. A real application for the oil supply chain is presented to show the applicability of the proposed model. It is aimed to show the SCOR 4.0 model can be used by both public and private sectors to improve their supply chain strategies in globalizing world.