Concern about air-quality in urban areas has led to the implementation of Low Emission Zones as one of many other initiatives to control it. Recently in Spain, the enactment of a law made this mandatory for cities with a population larger than 50k inhabitants. The delimitation of these areas is not without controversy because of possible negative economic and social impacts. Therefore, clear assessments of how these initiatives decrease pollutant concentrations are to be provided. Madrid Central is a major initiative of Madrid city council for reducing motor traffic and the associated air pollution in the city centre. This Low Emission Zone starts at the end of 2018, but the first fully-operational period corresponds to the second quarter of 2019. In this work, a methodology based on the Gaussian Process to analyse the evolution of Nitrogen Dioxide inside Madrid Central is undertaken. A Gaussian Process is a stochastic process suitable for interpretable model selection and predictions. Due to its probabilistic nature it provides error estimation at predictions. After the activation of Madrid Central, a relevant reduction of Nitrogen Dioxide has been observed. However, the role of the meteorology during this period must be ascertained to correctly evaluate the role of the activation of the Low Emission Zone against a prone weather. In this work, a model based on the Gaussian Process is trained with meteorological information to predict the concentration of Nitrogen Dioxide at Madrid Central, |$[NO_{2}]$|⁠. This probabilistic description allows extracting statistical information on the reduction affected by the meteorological scenario and separately by the Madrid Central activation.

Wildfires are increasingly recognized as a climatological hazard, able to threaten industrial and critical infrastructure safety and operations and lead to Natech disasters. Future projections of exacerbated fire regimes increase the likelihood of Natech disasters, therefore increasing expected direct damage costs, clean-up costs, and long-term economic losses due to business interruption and environmental remediation. While large industrial complexes, such as oil, gas, and chemical facilities have sufficient resources for the implementation of effective prevention and mitigation plans, small-to-medium-sized industrial hubs are particularly vulnerable due to their scattered distribution and limited resources for investing in comprehensive fire prevention systems. This study targets the vulnerability of these communities by proposing the deployment of Wireless Sensor Networks (WSNs) as cost-effective Early Wildfire Detection Systems (EWDSs) to safeguard wildland and industrial domains. The proposed approach leverages wildland–industrial interface (WII) geospatial data, simulated wildfire dynamics data, and mathematical optimization to maximize detection efficiency at minimal cost. The WII delimits the boundary where the presence of wildland fires impacts industrial activity, thus representing a proxy for potential Natech disasters. The methodology is tested in Cocentaina, Spain, a municipality characterized by a highly flammable Mediterranean landscape and medium-scale industrial parks. Results reveal the complex trade-offs between detection characteristics and the degree of protection in the combined wildland and WII areas, enabling stakeholders to make informed decisions. This methodology is easily replicable for any municipality and industrial installation, or for generic wildland–human interface (WHI) scenarios, provided there is access to wildfire dynamics data and geospatial boundaries delimiting the areas to protect.