Many applications of microwave energy to wooden materials have been developed in the lastfew decades, both for treatment and for diagnostic purposes. All these applications require a reliable estimation of the permittivity of the wood species of interest, which is the physical parameter ofcrucial importance in the absorption of electromagnetic energy. This paper presents results obtained in the dielectric characterization of five wood species in the frequency range from 2 to 3 including the ISM frequency of 2.45 GHz. Permittivity was measured by an open-ended coaxial-line probe of new design on wood samples conditioned at several moisture levels. The influence of the natural variability of wood characteristics on the measured pennittivity was also investigated by a suitable experimental setup consisting of a poplar table including both sapwood and heartwood regions. Finally, a theoretical discussion on the meaning of a scalar measurement on anisotropic dielectrics is conducted in terms of an isotropic-equivalent permittivity, which is related to the permittivity tensor of the dielectric material.
22 January 2010 in Analytical and Bioanalytical Chemistry
Calcium oxalates are insoluble colorless or whitish salts constituting noble patina, on both natural and artificial stone artworks' surfaces, the presence of which is extremely valued. The oxalates are not considered detrimental to the substrate, however, being often accompanied by other substances such as gypsum, silicates, and pigmented particles. They may form very adherent, relatively thick and colored layers creating disfiguring effects and hindering legibility of the pictorial surface. For this reason it may be appropriate to diminish their thickness, but patina's partial preservation is particularly required calling for extremely gradual and controllable cleaning approach. Thinning of calcium oxalate patina from a detached 16th century fresco (from Sansepolcro) was performed through the use of laser (Nd:YAG and Er:YAG) systems and chemical means (Carbogel loaded 5 wt.% of tetrasodium EDTA). Optical coherence tomography (OCT), providing a non-invasive stratigraphic cross-section of the examined surface, allowed to distinguish the oxalate from the underlying original layers and therefore to have an overview about its distribution, to numerically evaluate patina's thickness range and to provide the information on the amount of the material both removed and left on the artwork's surface. Laser scanning conoscopic microprofilometry allowed for a high-density sampling of the artwork's surface providing a three-dimensional model of the surface pattern. The obtained 3D models were used to estimate the amount of material removed and to compare them with those provided by OCT. The successful exploitation of the proposed exceptional cleaning monitoring methodology may be seen as an innovative and valid support for the restorers in the conservation of mural painting or other surfaces covered by oxalate layers and may pilot more targeted, cautious and respectful cleaning intervention.
17 July 2006 in Measurement Science and Technology
An open-coaxial probe suitable for measuring the permittivity of solid materials has been designed and tested. The peculiar structure of the probe allows an easy and firm contact with the surface of the material under measurement, resulting in highly reliable and reproducible dielectric measurements. The permittivity measurement is absolute, as the calibration procedure - based on a genetic algorithm - does not require the use of dielectric standards. The measurement system - including the probe, a network analyser, and the numerical code to determine the permittivity from reflection measurements - have been tested on solid materials of known properties, and used for determining the dielectric characteristics of several types of wood.
16 September 2016 in Structural Control and Health Monitoring