A mechanistic model on catalyst deactivation by coke formation in a continuous stirred tank reactor (CSTR) has been developed in the paper. Catalyst deactivation by coke formation was treated as a surface reaction. Four reaction mechanisms representing coke formation through different routes were proposed. The evolved system of ordinary differential equations (ODEs) was solved numerically using MATLAB. This approach was validated by applying it to the skeletal isomerization of 1-pentene over ferrierite. Simulation results were compared qualitatively to those obtained from the literature. Simulation results indicated that coke formation is an extremely rapid process with fast formation of coke components on the strongest acid sites leading to final coke. The coke deposition is slower at higher residence times resulting in more stable product formation and weaker deactivation. The results obtained from this work revealed that the developed model is indeed able to successfully demonstrate the most essential features of catalyst deactivation by coke formation and are in agreement with the findings in the literature. Future work is aimed to extend the study to different reactors such as a plug flow reactor, in addition to analysis of the reaction system’s sensitivity to variables such as temperature and pressure.

Understanding the behaviour of gas–liquid flows in upward and downward pipe configurations in chemical, petroleum, and nuclear industries is vital when optimal design, operation, production, and safety are of paramount concern. Unfortunately, the information concerning the behaviour of such flows in large pipe diameters is rare. This article aims to bridge that gap by reporting air–water upward and downward flows in 127 mm internal diameter pipes using advanced conductance ring probes located at two measurement locations. The liquid and gas flow rates are 0.021 to 0.33 m/s and 3.52 to 16.1 m/s, correspondingly, covering churn and annular flows. To achieve the desired objectives, several parameters, probability density function (PDF), power spectral density (PSD), Slippage Number (S_N), drift velocity (U_gd), and distribution coefficient (C₀) were employed. The flow regimes encountered in the two pipe configurations were distinguished employing a flow regime map available in the literature and statistical analysis. The obtained results were supported by visual inspection. The comparison between the present study against reported studies reveals the same tendency for the measured experimental data. The Root Mean Square Error (RMSE) method within 4% was utilized in recommending the best void fraction prediction correlation for the downward and upward flows.