Introduction: Anterior cruciate ligament (ACL) injuries are among the most severe and frequent injuries in alpine skiing, often occurring in non-contact situations during high-demand turns. Various instrumental techniques were used to assess susceptibility to anterior cruciate ligament (ACL) injuries in alpine ski racers and recreational skiers. This cross-sectional exploratory study aimed to identify key factors contributing to ACL injury susceptibility, comparing lab-based and on-snow tests. Materials and Methods: We examined nine elite ski racers and nine recreational skiers with strong athletic backgrounds. Skiing technique was analyzed using an instrumented insole system (CARV) to measure body position, pressure symmetry, and edge angle. Dynamic Q-angle symmetry during single-leg squats were assessed with an optical system (DynaKnee), while balance, strength, and agility were evaluated through ACL-specific lab tests (CoRehab). Group comparisons were performed using the nonparametric Mann–Whitney U test. Results: No significant differences were found between groups in ACL-specific lab tests, including balance, agility, and jump performance. However, ski racers exhibited 34.9% higher asymmetry in the Q-angle symmetry index during the one-leg squat. In contrast, ski technique differences were significant: ski racers achieved 16.3% higher Edge Similarity, 48% better Pressure Symmetry, and 5.8% better Fore-Aft Balance compared to recreational skiers. Conclusions: Despite similar general athletic abilities, elite skiers showed higher Q-angle asymmetry, which has been previously associated with ACL injury risk. However, their advanced skiing technique may partially mitigate the functional consequences of this asymmetry during on-snow tests. This suggests that refined skiing skills may influence functional performance in racing conditions, while pronounced one-sided dominance could indicate potential injury risk.