Modification of zeolitic structures through the incorporation of transition metal oxides has proven to be a promising approach for heterogeneous catalysis. In the present study, *BEA zeolite was modified using the incipient wetness impregnation method with varying amounts (10, 20, and 40 wt.%) of iron(III) oxide to investigate its structural and physicochemical properties. Characterization techniques such as XRD, UV–Vis DRS, FT–IR, Raman spectroscopy, SEM/EDS, TEM/EDS, and SAED, as well as textural and thermal analyses, were employed to assess the main changes. Different iron species were detected, including isolated iron(III) and well-dispersed Fe₂O₃ nanoparticles coating the zeolite surface. Under the synthesis conditions, increased Fe₂O₃ loading promoted hematite nanocrystal growth and the formation of the α-Fe₂O₃ phase, as demonstrated by XRD, Raman, and SAED analyses. Key observations included the preservation of the zeolite framework, high relative crystallinity (ranging from 70% to 85%), and a band gap of approximately 2.0 eV. Furthermore, a general increase in mesoporosity and external surface area was observed, along with a reduction in the number of acidic sites. This decrease may be attributed to restricted accessibility of the probe molecule (pyridine) to Brønsted sites due to micropore blockage in *BEA. These results demonstrate that the adopted synthesis method effectively produced α-Fe₂O₃/BEA catalysts, with no other crystalline phases of iron(III) oxide detected.