The interface between the matrix and reinforcing phases can have a significant effect on the mechanical properties of the resulting composite material. The interface can be studied by a number of surface analysis techniques and the interaction modelled. Such studies, and such modelling, can help understanding of the mechanisms which composites undergo during their lifetime. The current review discusses the role of the interface and the methods by which it can be studied; two case studies are presented which illustrate these methods and the value that such knowledge of the interface has brought to larger investigations.

Composite materials, such as carbon fibre reinforced epoxies, provide more efficient structures than conventional materials through light-weighting, but the associated high energy demand during production can be extremely detrimental to the environment. Biocomposites are an emerging material class with the potential to reduce a product’s through-life environmental impact relative to wholly synthetic composites. As with most materials, there are challenges and opportunities with the adoption of biocomposites at the each stage of the life cycle. Life Cycle Engineering is a readily available tool enabling the qualification of a product’s performance, and environmental and financial impact, which can be incorporated in the conceptual development phase. Designers and engineers are beginning to actively include the environment in their workflow, allowing them to play a significant role in future sustainability strategies. This review will introduce Life Cycle Engineering and outline how the concept can offer support in the Design for the Environment, followed by a discussion of the advantages and disadvantages of biocomposites throughout their life cycle.

Innovation is critical to business. Sustainability is a global challenge requiring innovation. Many organizations have publicly committed to innovate towards environmental, social and economic sustainability, but a behaviour gap remains. In order to promote the effectiveness of these endeavours, there is a pressing need to understand the conditions for successful innovation towards sustainability, backed by empirical evidence. This paper complements prior work by developing a definition of sustainability-oriented innovation (building upon definitions of eco-innovation), and by discussing observations of this activity in practice. The paper presents an account of sustainability-oriented innovation at Interface, a global manufacturing company with radical sustainability goals. It expounds the contexts in which these innovations arose, focusing in particular on Net-Works, a radical, socially-minded fishing-net recycling programme. It was found that several unique factors contributed to success: adopting an existing route to market, partnering with an NGO, and learning from mistakes in a “safe failure space”

The surface of 316 stainless steel has been modified using cold atmospheric plasma (CAP) to increase the surface free energy (by cleaning the and chemically activating the surface)IN preparation for subsequent processes such as painting, coating or adhesive bonding. The analyses carried out, on CAP treated 316 stainless steel surfaces, includes X-ray photoelectron spectroscopy (XPS), imaging XPS (iXPS), and surface free energy (SFE) analysis using contact angle measurements.The CAP treatment is shown to increase the SFE of as-received 316 stainless steel from ~39 mJ m-1 to >72 mJ m-1 after a short exposure to the plasma torch. This was found to correlate to a reduction in adventitious carbon, as determined by XPS analysis of the surface. The reduction from ~90 at% to ~30% and ~39 at%, after being plasma treated for 5 minutes and 15 seconds respectively, shows that the process is relatively quick at changing the surface. It is suggested that the mechanism that causes the increase in surface free energy is chain scission of the hydrocarbon contamination triggered by free electrons in the plasma plume followed by chemical functionalisation of the metal oxide surface and some of the remaining carbon contamination layer

Bio-derived fibres and resins are of increasing interest as alternatives to petrochemicals in the production of so-called environmentally friendly composite materials. However, whilst the majority of systems consider complete replacement, another route is to look at the constituents that are required to give certain properties, including the content of diluents; a third is to identify ‘hot spots’ in manufacturing. This paper considers these three possibilities in the context of the production of a resin system, and presents results from a life cycle assessment. The aim of this study was to make qualitative assertions based on quantitative estimates. The current work provides a practical assessment of the contribution of the manufacturing process of a multi-part resin formulation to a range of environmental impacts. As a part of this, a multi-stage methodology, the first of its kind, which is more relevant for the batch processes used to manufacture many structural thermosetting polymer systems, was developed. This was applied to a range of resins, some of which include bio-mass derived precursors. For the boundary conditions used, the indications are that the impacts due to taking the constituents and processing them to produce the resin system are insignificant compared with those due to producing the feedstocks in the first place. Surprisingly, whether the feedstocks were from fossil resources or were bioderived was of little significance. As a consequence of the analysis, it has been demonstrated that whilst a manufacturer can make significant savings through careful management of plant and the supporting energy mix, significant improvements to the environmental impacts of resin systems can be made through the choice of particular monomers.