The performance of synchrotron beamlines critically depends on the optimal coupling between the undulator and the monochromator. This work presents the implementation and quantitative characterization of a synchronized scanning system for the elliptically polarizing undulator (EPU) and the variable-line-spacing plane-grating monochromator at the BL07U beamline of the Shanghai Synchrotron Radiation Facility (SSRF). The system ensures that the monochromator’s narrow bandwidth dynamically tracks the brilliant central cone of the undulator radiation. A linear correlation between the monochromator energy and the undulator gap, justified theoretically for small scan ranges and reinforced by a robust real-time calibration procedure, forms the control basis. The automation is built upon a standard software stack comprising EPICS for device control, the Bluesky Suite for experimental orchestration, and Phoebus for the human–machine interface. Through comparative X-ray absorption spectroscopy (XAS) measurements at the Fe L_2,3-edges, the synchronized mode is shown to enhance beam brilliance by 37% and stabilize the incident flux, reducing its variation from 4.2% to 1.8%. This directly results in absorption spectra with superior lineshape fidelity, a 40% reduction in noise, and the elimination of pre- and post-edge artifacts, unequivocally isolating the synchronization effect. This advancement provides a stable, high-brilliance photon source essential for high-quality XAS and X-ray magnetic circular/linear dichroism (XMCD/XMLD) studies.