Laser cladding technology is a surface modification technology emerging in recent years, and it is widely used in the marine engineering field. Since the structural steels used in marine engineering are mostly carbon steels, their wear resistance and corrosion resistance are poor. In this paper, 316 L stainless steel/TiC composite coatings with different Y2O3 addition amounts were fabricated on Q355B steel surface using the laser cladding technology, and the phase composition, microstructure, microhardness, wear resistance, and corrosion resistance of the coatings were investigated with an X-ray diffractometer (XRD), a scanning electron microscope (SEM), a digital microhardness tester, a friction and wear tester, and an electrochemical workstation. When Y2O3 is added, the crystals in the bottom part of the coating are basically broken and the organisation becomes more dense. When the Y2O3 addition amount is 2%, the hardness is highest, the frictional coefficient curve of the coating exhibits a stable descending trend, and the coating mass loss is the lowest. When Y2O3 is added at 1%, the dynamic potential polarisation curve shows high corrosion potential and low corrosion current density and exhibited the best performance in EIS. The added Y2O3 evidently improves the wear resistance and corrosion resistance of 316 L stainless steel/TiC composite coatings, and this provides a new possibility that a composite coating modified with rare earth oxide is used for repair of marine engineering structures.
Laser cladding technology is used to fabricate CoCrFeNi HEA/WC composite coatings with different mass fractions of WC on the surface of 316L stainless steel. The microstructures of HEA/WC composite coatings were analyzed by combining multiple characterization techniques. The results show that the HEA/WC composite coatings have good surface formation without pores and hot cracks, and the metallurgical bonding is well formed between the coating and the 316L SS substrate. Under the action of a laser beam and molten pool, WC particles partially or slightly melt and diffuse to the matrix, which hinders the orderly growth of grains and forms multiple strengthening. The phase structure of the HEA/WC composite coatings is composed of a main phase with FCC. The hardness and corrosion resistance of the HEA/WC composite coatings are clearly enhanced, and the HEA/WC composite coating with 5% WC has optimum properties.
A Ni60+30%WC composite coating was prepared on the surface of Q235 steel by utilizing a high cooling rate, small thermal deformation of the substrate material, and the good metallurgical bonding characteristics of laser cladding technology. This paper focuses on the study of the composite coatings prepared under different process parameters in order to select the optimal process parameters and provide theoretical guidance for future practical applications. The macroscopic morphology and microstructure of t he composite coatings were investigated with the help of an optical microscope (OM) and a scanning electron microscope (SEM). The elemental distribution of the composite coatings was examined using an X-ray diffractometer. The microhardness and wear resistance of the composite coatings were tested using a microhardness tester, a friction tester, and a three-dimensional (3D) profilometer. The results of all the samples showed that the Ni60+30%WC composite coatings prepared at a laser power of 1600 W and a scanning speed of 10 mm/s were well formed, with a dense microstructure, and the microhardness is more than four times higher than the base material, the wear amount is less than 50% of the base material, and the wear resistance has been significantly improved. Therefore, the experimental results for the laser power of 1600 W and scanning speed of 10 mm/s are the optimal process parameters for the preparation of Ni60+30%WC.
To improve the corrosion resistance of 316L substrate and lengthen its useful life in marine environments, Ni-based/WC/Y2O3 cladding layers with different Y2O3 contents were fabricated on 316L stainless steel using laser cladding technology. The influence of Y2O3 additives on the microstructure and properties of the cladding coatings was investigated by using scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, a microhardness tester, an electrochemical workstation and a tribometer. Results show that the metallurgical bonding is well formed between the coating and the 316L substrate. The coating consisted primarily of γ-Ni phase and carbides. Adding an appropriate amount of Y2O3 can effectively refine the microstructure and inhibit the precipitation of the carbide hard phase; in addition, the added rare earth element can promote the solid-solution-strengthening effect of the cladding coatings, thus improving the microhardness and wear resistance of the cladding coatings and their electrochemical corrosion property in 3.5 wt% NaCl solution. The hardness of the Ni-based/WC coatings was substantially higher than that of the substrate, and it was greatest at a Y2O3 content of 1%. The corrosion and wear resistance of Y2O3-modified Ni-based/WC composite coatings are significantly better than those of the composite coating without Y2O3.
In this study, Ni60-WCx coatings (x = 0, 2, 4, 6 %) on 316L stainless steel (316Lss) were prepared via laser cladding technology. We examined all specimens s for microstructure, phase composition, microhardness and electrochemistry using several characterization techniques. It shows that the microstructure of the Ni-based coatings can be changed with WC powder. When the WC ratio is 2 %, crystalline crystals and cellular crystals can be found in the coating. As the WC ratio increases, more cellular crystals and fewer spiny crystals appear in the coating. When the WC ratio changes to 6 %, only cellular crystals can be found in the coating. The microhardness resultsshow that the Ni-based overcoat with added WC has a better microhardness compared to the pure Ni coating, and its average value of the coating area reaches a maximum value of 822.8 HV at a WC ratio of 2 %. That is due to the addition of WC which can cause regime transition. In addition, the Ni-based coating has better corrosion properties due to its different microstructure. When the WC ratio is 2 %, the specimen possesses the maximum Ecorr and smaller icorr with the best corrosion resistance.