Large-scale underground hydrogen storage in saline aquifers requires an understanding of hydrogen–brine two-phase flow properties, particularly relative permeability, which influences reservoir injectivity and hydrogen recovery. However, such hydrogen–brine relative permeability data remain scarce, hindering the predictive modeling of hydrogen injection and withdrawal. In this study, steady-state hydrogen–brine co-injection coreflood experiments were conducted on an Austin Chalk core sample to measure the relative permeabilities. Klinkenberg slip corrections were applied to the gas flow measurements to determine the intrinsic (slip-free) hydrogen permeability. The core’s brine permeability was 13.2 mD, and the Klinkenberg-corrected hydrogen gas permeability was 13.8 mD (approximately a 4.5% difference). Both raw and slip-corrected hydrogen relative permeability curves were obtained, showing that the gas-phase conductivity increased as the water saturation decreased. Gas slippage caused higher apparent gas permeability in the raw data, and slip correction significantly reduced hydrogen relative permeability at lower hydrogen saturations. The core’s irreducible water saturation was 39%, at which point the hydrogen relative permeability reached 0.8 (dropping to 0.69 after slip correction), which is indicative of strongly water-wet behavior. These results demonstrate a measurable impact of gas slippage on hydrogen flow behavior and highlight the importance of accounting for slip effects when evaluating hydrogen mobility in brine-saturated formations.

Underground hydrogen storage (UHS) in saline aquifers offers a viable alternative to surface-based storage systems, which are limited by capacity constraints, high operational pressures, complex thermal regulation, low energy densities, and potential safety hazards. This study uses a fully compositional reservoir simulation model to evaluate hydrogen behavior in the Mt. Simon Sandstone in the Illinois Basin. The analysis focuses on the effects of hysteresis, solubility, diffusivity, and production well perforation location on recovery efficiency. Cyclic injection and withdrawal scenarios were simulated to assess storage performance and operational strategies. The results show that accounting for hydrogen diffusivity shows essentially unchanged withdrawal efficiency at 79%, the same as the base case. Solubility causes a slight decrease to 78%, while hysteresis leads to a more significant reduction to 63%. The location of injection well perforations also influences recovery: top-perforated wells increase efficiency from 60% after the first cycle to 74% after six cycles, whereas bottom-perforated injection wells increase efficiency from 56% to 79% over the same period. These findings emphasize the importance of accounting for multiphase flow dynamics and strategic well placement in optimizing UHS system performance. The insights contribute to advancing reliable, large-scale hydrogen storage solutions essential for supporting renewable energy integration and long-term energy security.