José Antonio Macario Legaz

Dr. José Antonio Macario Legaz


Research Focus & Metrics

Academic Career Length

7Years (2020-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
10 December 2020 in Membranes
Verified
Journal Article
Open access
PDF file
Asuncion Maria HidalgoAsuncion Maria Hidalgo
Asuncion Maria Hidalgo
GLGerardo León
Gerardo León
MGMaria Gomez
Maria Gomez
Maria Dolores MurciaMaria Dolores Murcia
Maria Dolores Murcia
EGElisa Gómez
Elisa Gómez
JLJosé Antonio Macario Legaz
José Antonio Macario Legaz
The removal of organic dyes in aquatic media is, nowadays, a very pressing environmental problem. These dyes usually come from industries, such as textiles, food, and pharmaceuticals, among others, and their harm is produced by preventing the penetration of solar radiation in the aquatic medium, which leads to a great reduction in the process of photosynthesis, therefore damaging the aquatic ecosystems. The feasibility of implementing a process of nanofiltration in the purification treatment of an aqueous stream with small size dyes has been studied. Six dyes were chosen: Acid Brown-83, Allura Red, Basic Fuchsin, Crystal Violet, Methyl Orange and Sunset Yellow, with similar molecular volume (from 250 to 380 Å). The nanofiltration membrane NF99 was selected. Five of these molecules with different sizes, shapes and charges were employed in order to study the behavior of the membrane for two system characteristic parameters: permeate flux and rejection coefficient. Furthermore, a microscopy study and a behavior analysis of the membrane were carried out after using the largest molecule. Finally, the Spiegler–Kedem–Katchalsky model was applied to simulate the behavior of the membrane on the elimination of this group of dyes.

7 December 2025 in Foods
Verified
Journal Article
Open access
PDF file
Asuncion Maria HidalgoAsuncion Maria Hidalgo
Asuncion Maria Hidalgo
JLJosé Antonio Macario Legaz
José Antonio Macario Legaz
JMJorge Saura Martínez
Jorge Saura Martínez
LTLuis Tortosa-Díaz
Luis Tortosa-Díaz
RNRUBEN LOPEZ NICOLAS
RUBEN LOPEZ NICOLAS
Fulgencio Marin-IniestaFulgencio Marin-Iniesta
Fulgencio Marin-Iniesta
Orange peel is suitable for reuse due to the quantity and variety of bioactive compounds it contains, such as pectins, sugars and hesperidin. This study designed a scheme for reusing orange peel extract (OPE) using membrane technologies. Initially, a 100 kDa ceramic membrane was used to separate the pectins and hesperidine from acids and sugars and obtain a clarified product. In the subsequent stage, two ultrafiltration membranes of 25 and 5 kDa were tested, improving the results in terms of product transmittance and obtaining permeates whose physical–chemical parameters are compatible with those established by the European Fruit Juice Association. These membranes did not achieve complete separation of monosaccharide sugars from disaccharides. Finally, a 200 Da nanofiltration membrane was used, which completely reduced the sucrose and pectin content, concentrating glucose and fructose by 40%, values higher than those obtained with the GR90PP membrane. In addition, calcium and magnesium ions were completely rejected. Color changes in the permeate and concentrate streams could be appreciated due to the high concentration produced when working in batches. The nanofiltration (NF) process obtained lower yields (approximately 30%) compared to ultrafiltration (approximately 85%).

26 April 2024 in Separations
Verified
Journal Article
Open access
PDF file
Asuncion Maria HidalgoAsuncion Maria Hidalgo
Asuncion Maria Hidalgo
JLJosé Antonio Macario Legaz
José Antonio Macario Legaz
MAMarta Abellan-Baeza
Marta Abellan-Baeza
TSTeresa Sánchez-Moya
Teresa Sánchez-Moya
RNRUBEN LOPEZ NICOLAS
RUBEN LOPEZ NICOLAS
Fulgencio Marin-IniestaFulgencio Marin-Iniesta
Fulgencio Marin-Iniesta
Fruit consumption guarantees the supply of most of the necessary nutrients for a complete and balanced diet, as it is a relevant source of vitamins, minerals, and antioxidants. In particular, pomegranate has very interesting medicinal properties, such as an anti-inflammatory effect and the protection of the cardiovascular system, among others. During pomegranate juice production, it appears cloudy and must be clarified to remove suspended solids such as colloids and high-molecular weight tannins. The membrane clarification process is a cost-effective alternative to the conventional methods, resulting in a high-quality product. In this work, the clarification of pomegranate juice using the Triple System Model F1 membrane module was carried out for the Mollar and Wonderful varieties with early and late maturity. Three ultrafiltration membranes with different molecular weight cut-off and different chemical compositions were used. The rejection coefficient and permeate flux (which represent the selectivity of the membranes and the process efficiency, respectively) were measured. GR-40PP showed the best results in terms of membrane selectivity and process efficiency, achieving adequate physicochemical juice parameters. Regarding the comparison of the maturity degree, in general terms, the Mollar variety showed better results. Ripe pomegranates showed greater selectivity, while the process efficiency was higher for the early samples.