Performance of an electronic device relies heavily on the availability of a suitable functional material. One of the simple, easy, and cost-effective ways to obtain novel functional materials with improved properties for desired applications is to make composites of selected materials. In this work, a novel composite of transparent n-type zinc oxide (ZnO) with a wide bandgap and a unique structure of graphene in the form of a graphene flower (GrF) is synthesized and used as the functional layer of a humidity sensor. The (GrF/ZnO) composite was synthesized by a simple sol–gel method. Morphological, elemental, and structural characterizations of GrF/ZnO composite were performed by a field emission scanning electron microscope (FESEM), energy-dispersive spectroscopy (EDS), and an x-ray diffractometer (XRD), respectively, to fully understand the properties of this newly synthesized functional material. The proposed humidity sensor was tested in the relative humidity (RH) range of 15% RH% to 86% RH%. The demonstrated sensor illustrated a highly sensitive response to humidity with an average current change of 7.77 μA/RH%. Other prominent characteristics shown by this device include but were not limited to high stability, repeatable results, fast response, and quick recovery time. The proposed humidity sensor was highly sensitive to human breathing, thus making it a promising candidate for various applications related to health monitoring.
Biopolymers are a solution to solve the increasing problems caused by the advances and revolution in the electronic industry owing to the use of hazardous chemicals. In this work, we have used egg white (EW) as the low-cost functional layer of a biocompatible humidity sensor and deposited it on gold (Au) interdigitated electrodes (IDEs) patterned through the state-of-the-art fabrication technology of thermal vacuum evaporation. The presence of hydrophilic proteins inside the thin film of EW makes it an attractive candidate for sensing humidity. Usually, the dependence of the percentage of relative humidity (%RH) on the reliability of measurement setup is overlooked for impedimetric humidity sensors but we have used a modified experimental setup to enhance the uniformity of the obtained results. The characteristics of our device include almost linear response with a quick response time (1.2 s) and fast recovery time (1.7 s). High sensitivity of 50 kΩ/%RH was achieved in the desirable detection range of 10–85%RH. The device size was intentionally kept small for its potential integration in a marketable chip. Results for the response of our fabricated sensor for dry and wet fingertips, along with determining the rate of breathing through the mouth, are part of this study, making it a potential device for health monitoring.
Self-powered sensors are critically important for IoT, yet most rely on synthetic polymers that lack environmental sustainability. This work presents a triboelectric nanogenerator (TENG) made from marine biowaste which operates as both an energy generator and humidity sensor. Abalone shell powder (ASP) majorly composed of calcium carbonate (CaCO3) was used as its tribopositive layer in combination with polytetrafluoroethylene (PTFE) as tribonegative layer. The developed ASP-TENG device generated 410 V peak to peak open-circuit voltage (VOC) and 2.79 W·m−2 peak power density at an operating frequency of 4 Hz. These obtained results match or surpass existing biowaste-based TENGs. ASP-TENG efficiently worked as a self-powered humidity sensor because its output voltage decreased steadily from 410 V to 176 V in response to an increase in relative humidity (%RH) from 40% to 80% (decreases of 5.8 V for every 1%RH). The triboelectric charges become screened by water molecules that adsorb onto the porous CaCO3 surface which leads to faster leakage current. This work demonstrates a sustainable method to create TENGs with multiple functions while developing environmentally friendly sensing systems for environmental tracking and sustainable energy harvesting.