A novel α-cyanostilbenic derivative, (Z)-2-(4-aminophenyl)-3-(4-(dodecyloxy)phenyl) acrylonitrile, is reported, wherein a Z–E isomerization process is accompanied by a remarkable decrease in compatibility with liquid crystals. Accordingly, fluorescent-molecule-dispersed liquid crystals have been prepared through a photoisomerization-induced phase separation method. The photoluminescence can be repeatedly switched by an electric field. Modulating the excitation light offers a new technique to explore electrically controllable photoluminescence.
A novel luminescent liquid crystal, (2Z,2′Z)-2,2′-(1,4-phenylene)bis(3-(4-(dodecyloxy)phenyl)acrylonitrile) (PDPA), is reported, which shows green, yellow and orange colors depending on the self-assembled structure. The luminescence of PDPA can vary between those three different colors invoked by mechanical shearing and thermal annealing. Moreover, an excellent liquid crystal phase transition of PDPA is observed using polarized optical microscopy (POM) and differential scanning calorimetry (DSC) analysis. Finally, a prototype device is fabricated that demonstrates rewritable fluorescence optical recording with multistimuli luminescence tuning.
27 September 2019 in Inorganic Chemistry Frontiers
This review focuses on Sb2S3 solar cell functional layers, including their preparation methodologies, morphologies, structures, and photovoltaic performance.
An electrically tuned phase shifter based on the single slot unit cell and liquid crystal for a reconfigurable reflectarray antenna was presented. The simulation and measured results obtained at the F-band were used to demonstrate that the dielectric properties of a nematic state liquid crystal could be exploited to realize a slot unit cell phase shifter for the reconfigurable reflectarrays antennas. By reducing the inhomogeneous of the external electric field in the liquid crystal layer, a lower control voltage and improved model accuracy was obtained. In the experiments test, the achieved saturation bias voltage (10 V) was smaller than the previously reported structure, and the phase shift of the reflectarray greater than 300° was achieved in the frequency range 121.5–126 GHz. The maximum phase shift of 306° occurred at 124.5 GHz.
Electrically responsive photonic crystals represent one of the most promising intelligent material candidates for technological applications in optoelectronics. In this research, dye-doped polymer-stabilized cholesteric liquid crystals (PSCLCs) with negative dielectric anisotropy were fabricated, and mirrorless lasing with an electrically tunable wavelength was successfully achieved. Unlike conventional liquid-crystal lasers, the proposed laser aided in tuning the emission wavelength through controlling the reflection bandwidth based on gradient pitch distribution. The principal advantage of the electrically controlled dye-doped PSCLC laser is that the electric field is applied parallel to the helical axis, which changes the pitch gradient instead of rotating the helix axis, thus keeping the heliconical structure intact during lasing. The broad tuning range () of PSCLC lasers, coupled with their stable emission performance, continuous tunability, and easy fabrication, leads to its numerous potential applications in intelligent optoelectronic devices, such as sensing, medicine, and display.