Improvements and good practices (GPs) in rural environments are often developed by peasants themselves and shared among trust-based networks. The level of adoption of GPs by peasant family farmers (PFF) has been poorly studied. This paper describes the performance and results of the innovation adoption index (InAI) and rate (InAR) which were used to estimate the adoption of GPs for pesticide and veterinary drug use by PFF from eight different regions of Chile. Surveys were conducted among 257 farmers to find out about the adoption (yes/no) of a set of GPs in the adequate handling, use and storage of these chemical products, as well as some identifying information. The farmers in this study are producers of berries, dairy cows, honey and vegetables. The results of the survey showed an average of 57.33% GPs were adopted by farmers. Group averages of 55.23–61.32% were observed in the numbers of practices adopted by farmers. This survey data collection was part of a wider study intended to design a national plan to reduce chemical residues in food produced by PFF in Chile, with a focus on organizing practical workshops with extension officers and farmers.