Strontium isotopes in various marine carbonates were determined using an “AXIOM” MC-ICP-MS in combination with a NewWave UP193 laser ablation unit. Using a modified measurement and data reduction strategy, an external reproducibility of 87Sr/86Sr ratios in carbonates of about 19 ppm (RSD) was achieved. For recent and sub-recent marine carbonates a mean radiogenic strontium isotope ratio 87Sr/86Sr of 0.709170 ± 0.000007 (2SE) was determined, which agrees well with the value of 0.7091741 ± 0.0000024 (2SE) reported for modern sea water (J. M. McArthur, D. Rio, F. Massari, D. Castrodi, T. R. Bailey, M. Thirlwall and S. Houghton, Palaeogeogr. Palaeoclimatol. Palaeoeco., 2006, 242(126), 2006). Compared to published laser-based methods, an improved accuracy and precision was achieved by applying a new data reduction protocol using the simultaneous responses of all isotopes measured. The latter is considered as a new principal approach for isotope ratio evaluation using LA-MC-ICP-MS. A major advantage of the presented method is the direct determination of the stable strontium isotope fractionation. Providing reproducible sample ablation, introduction into the plasma and stable plasma condition, this method excludes the efforts of a quantitative strontium recovery after ion chromatographic separation to avoid additional fractionation of the sample strontium due to chemical pre-treatment/separation (ion chromatography and solution preparation), and is therefore, together with the quicker sample preparation and spatially resolved analysis, advantageous when compared to published solution–nebulization bracketing-standard MC-ICP-MS methods for stable strontium isotope determination.
The growth of large volcanoes is commonly interrupted by episodes of flank collapse that may be accompanied by catastrophic debris avalanches, explosive eruptions, and tsunamis. El Hierro, the youngest island of the Canary Archipelago, has been repeatedly affected by such mass-wasting events in the last 1 Ma. Our field observations and petrological data suggest that the largest and most recent of these flank collapses—the El Golfo landslide—likely influenced the magma plumbing system of the island, leading to the eruption of higher proportions of denser and less evolved magmas. The results of our numerical simulations indicate that the El Golfo landslide generated pressure changes exceeding 1 MPa down to upper-mantle depths, with local amplification in the surroundings and within the modeled magma plumbing system. Stress perturbations of that order might drastically alter feeding system processes, such as degassing, transport, differentiation, and mixing of magma batches
8 November 2008 in Contributions to Mineralogy and Petrology