This work investigated the mechanical and catalytic degradation properties of FeMnCoCr-based high-entropy alloys (HEAs) with diverse compositions and porous structures fabricated via selective laser melting (SLM) additive manufacturing for wastewater treatment applications. The effects of Mn content (0, 30 at%, and 50 at%) and topological structures (gyroid, diamond, and sea urchin-inspired shell) on the compression properties and catalytic efficiency of the Fe_80-xMn_xCo₁₀Cr₁₀ HEAs were discussed. The results indicated that an increase in the Mn content led to a phase structure transition that optimized mechanical properties and catalytic activities. Among the designed structures, the gyroid HEA structure exhibited the highest compressive yield strength, reaching 197 MPa. Additionally, Fe₃₀Mn₅₀Co₁₀Cr₁₀ HEA exhibited exceptional performance in catalytic degradation experiments by effectively degrading simulated pollutants with a significantly enhanced rate by 22.3% compared to other compositions. The Fe_80-xMn_xCo₁₀Cr₁₀ HEA catalyst fabricated by SLM demonstrated high stability over multiple cycles. These findings reveal that porous FeMnCoCr-based HEAs have significant potential for catalytic degradation of organic pollutants, providing valuable insights for future catalyst design and development in efficient and sustainable wastewater treatment.

Wire arc directed energy deposition (WA-DED) is a cost-effective technique for fabricating large metallic components. However, the inherent layer-by-layer deposition process leads to substantial heat accumulation, which significantly influences the resulting microstructure and mechanical properties. In this study, the effects of thermal cycling histories, at different interlayer temperatures, on the microstructural evolution and mechanical behavior of WA-DED fabricated H13 steel thin walls were systematically investigated, using an experimentally calibrated transient thermal model combined with experimental validation. Microstructural analysis revealed that at an interlayer temperature of 200 °C, the deposited material primarily consisted of coarse martensite with a low dislocation density and relatively large precipitates at a moderate volume fraction, resulting in an ultimate tensile strength of 1103 ± 28 MPa and an elongation of 14.6%. Increasing the interlayer temperature to 400 °C facilitated the formation of finer martensite with a higher dislocation density and smaller precipitates of slightly increased volume fraction. These microstructural refinements enhanced the tensile strength to 1549 ± 43 MPa, albeit at the expense of ductility, reducing elongation to 8.3%. When the interlayer temperature was further raised to 600 °C, fine martensite and a moderate dislocation density were retained; however, precipitate coarsening and a reduced volume fraction led to a decline in tensile strength to 1434 ± 33 MPa, accompanied by a slight recovery in elongation to 8.6%. Quantitative analysis based on classical strengthening models confirmed that dislocation strengthening is the dominant mechanism governing the variation in mechanical properties with changing interlayer temperature.