Biocompatible poly(lactic acid) (PLA) was plasticized with poly(ethylene glycol) (PEG) added at concentrations of 10, 15, and 20 wt.% relative to PLA, and then processed into gyroid triply periodic minimal surface (TPMS) scaffolds using fused filament fabrication (FFF) 3D printing. The influence of PEG concentration and gyroid structure (50% infill density) on thermal transitions, crystallinity, and low–temperature shape-memory performance was systematically investigated. The shape-memory effect (SME) of the PLA–based scaffolds was tailored through compositional control and structural design. Shape recovery under thermal activation at 40 °C and 50 °C was examined to reveal the correlation between composition and structure in governing low–temperature shape-memory behavior. The optimal composition (PLA/10 PEG, 50% gyroid infill) achieved shape recovery with a recovery ratio (Rr) of 97 ± 1% at 40 °C within 6 ± 1 min, demonstrating optimal shape-memory activation close to physiological temperature. Structural and morphological changes were characterized using ATR–FTIR, Raman spectroscopy, DSC, XRD, and SEM, providing comprehensive insight into the plasticization of the PLA matrix and its impact on structure–property relationships relevant to bone tissue engineering.
In this work, SiC–Ti3AlC2 and TiC–Ti3AlC2 composites produced by additive manufacturing are investigated. The issue of obtaining ceramic materials using additive manufacturing technologies is currently relevant, since not many modern additive technologies are suitable for working with ceramic materials. The study is devoted to the optimization of additive manufacturing parameters, as well as the study of the structure and properties of the resulting objects. The fused granules fabrication (FGF) method as one kind of the material extrusion additive manufacturing (MEAM) technology is used to obtain composite samples. The main advantage of the FGF technology is the ability to obtain high-quality samples from ceramic materials by additive manufacturing. Composites with different ratios between components and different powder/polymer ratios are investigated. The technological features of the additive formation of composites are investigated, as well as their structure and properties. The optimal sintering temperature to form the best mechanical properties for both composites is 1300 °C. The composites have a regulatable porosity. Ti3AlC2 content, sintering temperature, and polymer content in the feedstock are the main parameters that regulate the porosity of FGF samples.
In this work SiC-Ti3AlC2 and TiC-Ti3AlC2 composites produced by additive manufacturing are investigated. The fused granules fabrication (FGF) method as one of the material extrusion additive manufacturing (MEAM) technology is used to obtain composite samples. Composites with different ratios between components and different powder:polymer ratios are investigated. The technological features of the additive formation of composites are investigated, as well as their structure and properties. The optimal sintering temperature to form the best mechanical properties for both composites is 1300 °C. The composites have a regulatable porosity. Ti3AlC2 content, sintering temperature, and polymer content in the feedstock are the main parameters that regulates the porosity of FGF samples.
In this work, the samples of the WC-Fe-Ni-Co composition were obtained and studied. Alloy NiCo 29-18 is used as a binder (Fe-Ni-Co). In this paper, a comparative analysis of the samples obtained using commercial micron-sized WC powder and the samples obtained is carried out using nano-WC synthesized via the electric explosion of wire (EEW) method. The samples were subjected to vacuum sintering, then their structure, density, and porosity, as well as microhardness and oxidation resistance, were studied. Five different additives were used to stabilize sintering: VC, Cr3C2, NbC, Y2O3, and Nd2O3. All these additives are described in the literature as additives that are used in the sintering of materials of the WC-Co system. Also, the samples from the WC-Fe-Ni-Co material were obtained using additive manufacturing technology with material extrusion. Bending strength and hardness of the additively fabricated samples were determined.
2 August 2025 in Progress in Additive Manufacturing