Laser-induced breakdown spectroscopy (LIBS) has attracted a lot of attention due to its potential to rapidly identify and quantify any chemical element with minimal sample preparation. Despite continuous improvements, the sensitivity of this technique still remains a challenge. In order to increase LIBS intensity, a laser-induced fluorescence (LIF) system can be coupled with LIBS to re-excite a transition of the element in the plasma by employing very expensive optical parametric oscillators (OPO). In this work, a homemade tunable continuum wave-diode laser (CW-DL) has been developed and coupled to a double pulse (DP) LIBS system to enhance the sensitivity of Pb detection in a soil sample at the transition $6{\mathrm{s}}^{2}6{\mathrm{p}}^2\text{–}{{}^3\mathrm{P}}_2\to 6{\mathrm{s}}^{2}6\mathrm{p}7\mathrm{s}\text{–}{{}^3\mathrm{P}}_1$ at 405.78 nm. Before sample analysis, the production of no scattered light by the plasma was ascertained, and the optimal temperature of 10,000 K was estimated for this transition, feasible to be achieved in DP-LIBS systems. An increase of approximately 100% for the Pb I transition at 405.78 nm was obtained by DP-LIBS-CW-DL-LIF with respect to the DP-LIBS system alone. This result opens a new promising line of research to improve LIBS sensitivity using the CW-DL approach.

Laser-induced breakdown spectroscopy (LIBS) is showing to be a promising, quick, accurate, and practical technique to detect and measure metal contaminants and nutrients in urban wastes and landfill leachates. Although conventional LIBS presents some limitations, such as low sensitivity, when used in the single pulse configuration if compared to other spectroscopic techniques, the use of the double-pulse (DP) configuration represents an adequate alternative. In this work DP LIBS has been applied to the qualitative and quantitative analysis of mercury (Hg) in landfill leachates. The correlation analysis performed between each intensified charge-coupled device pixel and the Hg concentration allowed us to choose the most appropriate Hg emission line to be used for its measure. The normalization process applied to LIBS spectra to correct physical matrix effects and small fluctuations increased from 0.82 to 0.98 the linear correlation of the calibration curve between LIBS and the reference data. The limit of detection for Hg estimated using DP LIBS was $76{\mathrm{mg}\mathrm{Kg}}^{-1}$. The cross validation (leave-one-out) analysis yielded an absolute average error of about 21%. These values showed that the calibration models were close to the optimization limit and satisfactory for Hg quantification in landfill leachate.

Significant two-body losses are observed in an ultracold gas of ${}^{85}$Rb or ${}^{87}$Rb atoms in a crossed dipole trap implemented with a broadband laser with a wavelength around 1071 nm. Using available spectroscopic data on the excited states of Rb${}_{2}$, as well as accurate computed transition dipole moment functions, we interpret these losses as due to photoassociation of deeply bound levels of the 0${}_{u}^{+}$ coupled states by the trapping laser, followed by spontaneous emission down to bound levels of the Rb${}_{2}$ ground state thus forming ultracold molecules. The observed ratio of 3.3 between the loss rates of ${}^{87}$Rb and ${}^{85}$Rb is well reproduced by the theoretical model.