Superhydrophobic surfaces, characterized by water contact angles greater than 150°, have attracted widespread interest due to their exceptional water repellency and multifunctional applications. However, traditional fabrication methods often rely on fluorinated compounds and petroleum-based polymers, raising environmental and health concerns. In response to growing environmental and health problems, recent research has increasingly focused on developing green superhydrophobic surfaces, employing eco-friendly materials, energy-efficient processes, and non-toxic modifiers. This review systematically summarizes recent progress in the development of green superhydrophobic materials, focusing on the use of natural substrates such as cellulose, chitosan, starch, lignin, and silk fibroin. Sustainable fabrication techniques, including spray coating, dip coating, sol–gel processing, electrospinning, laser texturing, and self-assembly, are critically discussed with regards to their environmental compatibility, scalability, and integration with biodegradable components. Furthermore, the functional performance of these coatings is explored in diverse application fields, including self-cleaning, oil–water separation, anti-corrosion, anti-icing, food packaging, and biomedical devices. Key challenges such as mechanical durability, substrate adhesion, and large-scale processing are addressed, alongside emerging strategies that combine green chemistry with surface engineering. This review provides a comprehensive perspective on the design and deployment of eco-friendly superhydrophobic surfaces, aiming to accelerate their practical implementation across sustainable technologies.

Adding alloying elements to binary nitrides enables the design of hard and tough coatings. To improve the mechanical and tribological performances of TiN-based coatings, La atoms were added to TiAlN coatings to form TiAlLaN coatings. Magnetron sputtering was conducted to prepare the TiAlLaN coatings. Thereafter, scanning electron microscopy (SEM), x-ray diffraction (XRD), nano-indentation, and a tribometer were utilized to test their microstructure, phases, and mechanical and tribological performances. Next, this study analyzed how lanthanum affected the microstructure and tribological performances of the TiAlLaN coatings. Incorporating La atoms in TiAlN coatings reduced the crystallite size and enhanced the coating toughness and hardness. The hardness H and elastic modulus E of the TiAlLaN coatings first increased and then decreased with the increase in La. Meanwhile, the coatings had improved wear and friction properties. The increased H/E and H³/E² levels, which have been considered to reflect the hard coating’s toughness, were acquired based on the TiAlLaN coating, possessing enhanced hardness (19.8 GPa). The coefficient of friction and the wear rates of the coatings reduced and then increased with the increase in La. The TiAlLaN coating with 1.4 % of lanthanum had the lowest friction coefficient and wear rate of around 0.383 and 1.59 × 10⁻⁸ mm³/N·m, respectively, corresponding to a higher H/E (~0.086) and H³/E² (~0.147 GPa). Adding an appropriate amount of La can substantially enhance the TiAlN coating’s tribological and mechanical properties. The TiAlLaN coating with remarkable characteristics may be applied to a steel substrate.