Predicting runoff source areas and how they change through time is a challenge in hydrology. Topographically induced lateral water redistribution and water removal through evapotranspiration lead to spatially and temporally variable patterns of watershed water storage. These dynamic storage patterns combined with threshold mediation of saturated subsurface throughflow lead to runoff source areas that are dynamic through time. To investigate these processes and their manifestation in watershed runoff, we developed and applied a parsimonious but spatially distributed model (WECOH—Watershed ECOHydrology). Evapotranspiration was measured via an eddy‐covariance tower located within the catchment and disaggregated as a function of vegetation structure. This modeling approach reproduced the stream hydrograph well and was internally consistent with observed watershed runoff patterns and behavior. We further examined the spatial patterns of water storage and their evolution through time by building on past research focused on landscape hydrologic connectivity. The percentage of landscape area connected to the stream network ranged from less than 1% during the fall and winter base flow period to 71% during snowmelt. Over the course of the 2 year study period, 90% of the watershed areas were connected to the stream network for at least 1 day, leaving 10% of area that never became connected. Runoff source areas during the event shifted from riparian dominated runoff to areas at greater distances from the stream network when hillslopes became connected. Our modeling approach elucidates and enables quantification and prediction of watershed active areas and those active areas connected to the stream network through time.

The rainfall‐runoff response of watersheds is affected by the legacy of past hydroclimatic conditions. We examined how variability in precipitation affected streamflow using 21 years of daily streamflow and precipitation data from five watersheds at the Coweeta Hydrologic Laboratory in southwestern North Carolina, USA. The gauged watersheds contained both coniferous and deciduous vegetation, dominant north and south aspects, and differing precipitation magnitudes. Lag‐correlations between precipitation and runoff ratios across a range of temporal resolutions indicated strong influence of past precipitation (i.e., watershed memory). At all time‐scales, runoff ratios strongly depended on the precipitation of previous time steps. At monthly time scales, the influence of past precipitation was detectable for up to 7 months. At seasonal time scales, the previous season had a greater effect on a season's runoff ratio than the same season's precipitation. At annual time scales, the previous year was equally important for a year's runoff ratio than the same year's precipitation. Estimated watershed storage through time and specifically the previous year's storage state was strongly correlated with the residuals of a regression between annual precipitation and annual runoff, partially explaining observed variability in annual runoff in watersheds with deep soils. This effect was less pronounced in the steepest watershed that also contained shallow soils. We suggest that the location of a watershed on a nonlinear watershed‐scale storage‐release curve can explain differences in runoff during growing and dormant season between watersheds with different annual evapotranspiration.

Weathering is the ultimate source of solutes for ecosystems, controls chemical denudation of landscapes, and drives the geologic carbon cycle. Mining and other land‐moving operations enhance physical weathering by bringing large volumes of shattered bedrock to the surface. Yet, the relative influence of these activities on chemical weathering remains poorly constrained. Here we show that catchments impacted by mountaintop removal coal mining have among the highest rates of chemical weathering ever reported. Mined catchments deliver more than 7,600 kg·ha⁻¹·year⁻¹ of dissolved solids downstream. The chemical signatures of these exceptionally high weathering rates reflect the product of sulfuric acid weathering of carbonate‐bearing rock, driven by the oxidation of pyritic materials. As this strong acid rapidly weathers surrounding carbonate materials, H⁺ ions are consumed and Ca²⁺, Mg²⁺, and HCO₃⁻ ions are exported to balance the elevated SO₄²⁻ exports, generating alkaline mine drainage. The sulfate exports from pyrite oxidation in mountaintop‐mined catchments account for ~5–7% of global sulfate derived from pyrite, despite occupying less than 0.006% of total land area. Further, the suite of weathering reactions liberate 100–450 kg of rock‐derived C·ha⁻¹·year⁻¹ as CO₂, with an additional 90–150 kg C·ha⁻¹·year⁻¹ of C released when HCO₃⁻ reaches the ocean. This rock C release contributes to the high carbon costs of coal combustion.

Mountaintop removal coal mining (MTM) is a form of surface mining where ridges and mountain tops are removed with explosives to access underlying coal seams. The crushed rock material is subsequently deposited in headwater valley fills (VF). We examined how this added water storage potential affects streamflow using a paired watershed approach consisting of two sets of mined and unmined watersheds in West Virginia. The mined watersheds exported 7–11% more water than the reference watersheds, primarily due to higher and more sustained baseflows. The mined watersheds exported only ~1/3 of their streamflow during storms, while the reference watersheds exported ~2/3 of their annual water yield during runoff events. Mined watersheds with valley fills appear to store precipitation for considerable periods of time and steadily export this alkaline and saline water even during the dry periods of the year. As a result, MTMVFs in a mixed mined/unmined watershed contributed disproportionately to streamflow during baseflow periods (up to >90% of flow). Because MTMVFs have both elevated summer baseflows and continuously high concentrations of total dissolved solids, their regional impact on water quantity and quality will be most extreme and most widespread during low flow periods.

Mountaintop mining, like all forms of surface mining, fundamentally alters the landscape to extract resources that lie 10–100 ms below the land surface. Despite these deep, critical zone alterations, post-mining landscapes are required by United States law to be restored to ecosystems of equal or greater value than the ones they replace. Yet, remote sensing of vegetation across more than 1000 km² of reclaimed surface mines in WV, USA reveals little evidence that these habitats are returning to the diverse Appalachian forests that were removed by mining. Instead, even decades after reclamation, mined landscapes are dominated by shorter and sparser trees. Based on detailed field studies and literature synthesis, we suggest that part of these widespread failures in re-establishing native forest result from the fundamental changes in critical zone processes on the post-mining landscape. Former surface mines have substantially altered topography, hydrology and chemistry. In these post-mining, synthetic landscapes, water moves more slowly through piles of exploded bedrock, changing the system from one dominated by stormflow in unmined catchments, to one dominated by baseflow after mining. This slow-moving water, travelling through high surface-area debris and pyrite-rich bedrock, creates ideal conditions for highly elevated weathering in mines both old and new. These foundational changes to the critical zone set ecosystem recovery along a novel trajectory, in which the legacy of past disturbance is likely to constrain the establishment of native forest for many decades.