This study systematically investigates the influence of short carbon-fiber (SCF) content on the mechanical, thermal, and tribological properties of self-lubricating polyphenylene sulfide (PPS) composites filled with PTFE and MoS2, addressing the critical need for high-wear resistance in Carbon-Fiber-Reinforced Thermoplastic (CFRTP) structural applications. The results identified 10 wt% SCF as the optimal content that achieved the best balance between load-bearing capacity and friction performance. The coefficient of friction μ and wear amount were reduced by 29.28% and 29.29%, respectively, compared to the PPS/PTFE/MoS2 composite material without SCF, and by 14.67% and 20.75%, respectively, compared to the material with excessive SCF filling (20 wt%). Finite-Element Analysis-Representative Volume Element (FEA-RVE) reveals the mechanism by which excessive content of SCF at the microscopic level leads to a slight decrease in mechanical properties. Critically, the tribological performance exhibited a discrepancy with bulk mechanical properties: above 15 wt% SCF, the wear rate worsened despite high mechanical strength, revealing that increased fiber agglomeration and micro-abrasion effects were the primary causes of performance deterioration. Further in-depth XPS analysis revealed a synergistic lubrication mechanism: In the optimal sample, an ultra-dense PTFE transfer film was formed to mask the underlying MoS2. This masking, coupled with the high surface activity of MoO3 particles leads to stronger physicochemical interactions with the polymer matrix, ensures the exceptional durability and stability of the tribo-film. This research establishes a complete structure–performance relationship by integrating mechanical, thermal, and tribo–chemical mechanisms, offering critical theoretical guidance for the design of next-generation high-performance self-lubricating CFRTPs.
In the oil and gas pipeline industry, numerous small-diameter branch pipe fillet welds exist, which are prone to stress concentration because of diverse geometric shapes. The internal welding defects within these welds pose severe hazards to safe production. Specifically, the irregular geometry often leads to internal root defects where the weld metal fails to fully penetrate the joint or fuse with the base material (referred to as incomplete penetration and incomplete fusion). This study developed a GF-CF-GF (CF is carbon fiber, GF is glass fiber) sandwich composite reinforcement structure for pipe fittings with these specific internal defects (main pipe: Φ323.9 × 12.5 mm; branch pipe: Φ76 × 5 mm) through a combination of finite element analysis (FEA) and burst test verification. The inherent correlation between structural factors and pressure-bearing capacity was revealed by analyzing the influence of defect sizes. Based on FEA, the repair layer coverage should be designed to be within 400 mm from the defect along the main pipe wall direction and within 100 mm from the defect along the branch pipe wall direction, with required thicknesses of 5.6 mm for incomplete penetration and 3.2 mm for incomplete fusion. Analysis of the actual burst test pressure curve showed that the elastic-plastic transition interval of the repaired pipes increased by approximately 2 MPa compared to normal undamaged pipes, and their pressure-bearing capacities rose by 1.57 MPa (incomplete penetration) and 1.76 MPa (incomplete fusion). These results demonstrate the feasibility of the proposed reinforcement design, which has potential applications in the safety and integrity of oil and gas transportation.