The purpose of this research study is to present some new operations, including rejection, symmetric difference, residue product, and maximal product of Pythagorean fuzzy graphs (PFGs), and to explore some of their properties. This research article introduces certain notions, including intuitionistic fuzzy graphs of 3-type (IFGs3T), intuitionistic fuzzy graphs of 4-type (IFGs4T), and intuitionistic fuzzy graphs of n-type (IFGsnT), and proves that every IFG(n − 1)T is an IFGnT (for $n\ge$ 2). Moreover, this study discusses the application of Pythagorean fuzzy graphs in decision making.