Carbon fiber-reinforced polymer (CFRP) composites have been widely used in civil engineering structures due to their excellent mechanical and durability properties. The harsh service environment of civil engineering leads to significant degradation of the thermal and mechanical performances of CFRP, which then reduces its service reliability, service safety, and life. Research on the durability of CFRP is urgently needed to understand the long-term performance degradation mechanism. In the present study, the hygrothermal aging behavior of CFRP rods was investigated experimentally through immersion in distilled water for 360 days. The water absorption and diffusion behavior, the evolution rules of short beam shear strength (SBSS), and dynamic thermal mechanical properties were obtained to investigate the hygrothermal resistance of CFRP rods. The research results show that the water absorption behavior conforms to Fick’s model. The ingression of water molecules leads to a significant decrease in SBSS and glass transition temperature (Tg). This is attributed to the plasticization effect of the resin matrix and interfacial debonding. Furthermore, the Arrhenius equation was used to predict the long-term life of SBSS in the actual service environment based on the time–temperature equivalence theory, obtaining a stable strength retention of SBSS of 72.78%, which was meaningful to provide a design guideline for the long-term durability of CFRP rods.

In order to promote the engineering applications of carbon- and glass-fiber-reinforced epoxy hybrid rods, it is necessary to fully understand its long-term hygrothermal durability. In the present study, the water absorption behaviors of a hybrid rod in a water immersion environment are studied experimentally, the degradation rules of the mechanical properties are obtained, and establishing a life prediction model is attempted. The water absorption of the hybrid rod confirms to the classical Fick’s diffusion model, and the water absorption concentration is determined by radial position, immersion temperature, and immersion time. In addition, the radial position of water molecules diffused into the rod is positively correlated with the diffusion concentration. The short-beam shear strength of the hybrid rod decreased significantly after 360 days of exposure; this is because water molecules interact with the polymer through hydrogen bonds to produce bound water during the immersion process, leading to resin matrix hydrolysis and plasticization, as well as interfacial debonding. In addition, the ingression of water molecules caused degradation in the viscoelastic behavior of the resin matrix in hybrid rods. The glass transition temperature of hybrid rods decreased by 17.4% after exposure at 80 °C for 360 days. The Arrhenius equation was used calculate the long-term life of short-beam shear strength in the actual service temperature based on the time–temperature equivalence theory. The stable strength retention for SBSS was found to be 69.38%, which is a useful durability design parameter for hybrid rods in civil engineering structures.