Surface modification using Cu significantly improves the performance of Ru/MWCNT catalysts for the selective production of 1,2-PD up to (93.4%) from glycerol hydrogenolysis.

Dispersion of carbon nanoparticles in epoxy resin is the key factor to adjust the resulting electrical and mechanical properties of the nanocomposite. A profound understanding of the driving forces of standard methods like ultrasonic and mechanical dispersion is necessary. To derive the impact of applied frequency and strain on the resulting dispersion of multi-walled carbon nanotube (MWCNT)-filled epoxy resin, this work addresses the strain and frequency dependency of oscillatory shear flow-induced network changes. Strain- and frequency-sweeps were performed for a wide parameter set with in-line measurement of electrical DC resistance to monitor changes in the MWCNT network. Changes in electrical resistance reveal destruction and formation of the MWCNT network. A fundamental novel finding is the governing dependency of changes in the electrical network on applied shear amplitude. The applied frequency barely induces network changes. Applied shear rates do not correlate with particular network states.

A trade-off between enhancement of physical properties of the final part and the processability during manufacturing always exists for the application of nanocarbon materials in thermoset-based composites. For different epoxy resins, this study elaborates the impact of nanocarbon particle type, functionalization, and filler loading on the resulting properties, i.e., rheological, electrical, thermo-mechanical, as well as the fracture toughness in mode I and mode II loading. Therefore, a comprehensive set of carbon nanoparticles, consisting of carbon black (CB), single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), few layer graphene (FLG), and electrochemically expanded graphite (ExG), in purified or functionalized configuration was introduced in various epoxy resins, with different molecular weight distributions. A novel technique to introduce sharp cracks into single-edge notched bending (SENB) fracture toughness specimens led to true values. SWCNT show highest potential for increasing electrical properties without an increase in viscosity. Functionalized MWCNT and planar particles significantly increase the fracture toughness in mode I by a factor of two.