Inverse magnetic fabrics defined by anisotropy of magnetic susceptibility with the longest principal axis perpendicular to bedding were identified in the studied samples of Ordovician sedimentary rocks from the Barrandian area, Czech Republic. These fabrics are related to ankerite fibers in association with cone‐in‐cone structures. To understand the meaning of such inverse magnetic fabrics for geological interpretations, a new, more detailed classification of inverse magnetic fabrics' types is formulated in this paper. Distinguishing the structural (i.e., shape) and magnetocrystalline anisotropies in rocks, three new (sub)types of magnetic fabrics were defined in this study based on the combination of structural normal/inverse and magnetocrystalline normal/inverse anisotropies. As a result, normal magnetic fabric is extended by new fabric types associated with inverse anisotropy: simple inverse, pure inverse, and pseudo‐normal magnetic fabrics. The studied fibrous ankerite shows simple inverse magnetic fabric, which results from the combination of normal magnetocrystalline and inverse structural anisotropies.
Beta-titanium alloys are promising materials for bone implants due to their advantageous mechanical properties. For enhancing the interaction of bone cells with this perspective material, we developed a ferroelectric barium titanate (BaTiO3) coating on a Ti39Nb alloy by hydrothermal synthesis. This coating was analyzed by scanning electron and Raman microscopy, X-ray diffraction, piezoresponse force microscopy, X-ray photoelectron spectroscopy, nanoindentation, and roughness measurement. Leaching experiments in a saline solution revealed that Ba is released from the coating. A progressive decrease of Ba concentration in the material was also found after 1, 3, and 7 days of cultivation of human osteoblast-like Saos-2 cells. On day 1, the Saos-2 cells adhered on the BaTiO3 film in higher initial numbers than on the bare alloy, but they were less spread, and their initial proliferation rate was slower. These cells also contained a lower amount of beta1-integrins and vinculin, i.e., molecules involved in cell adhesion, and produced a lower amount of collagen I. This cell behavior was attributed to a higher surface roughness of BaTiO3 film rather than to its potential cytotoxicity, because the cell viability on this film was very high, reaching almost 99%. The amount of alkaline phosphatase, an enzyme involved in bone matrix mineralization, was similar in cells on the BaTiO3-coated and uncoated alloy, and on day 7, the cells on BaTiO3 film attained a higher final cell population density. These results indicate that after some improvements, particularly in its roughness and stability, the hydrothermal ferroelectric BaTiO3 film could be promising coating for improved osseointegration of bone implants.
The influence of Mo on the electronic states and crystalline structure, as well as morphology, phase composition, luminescence, and defects in ZnO rods grown as free-standing nanoparticles, was studied using a variety of experimental techniques. Mo has almost no influence on the luminescence of the grown ZnO particles, whereas shallow donors are strongly affected in ZnO rods. Annealing in air causes exciton and defect-related bands to drop upon Mo doping level. The increase of the Mo doping level from 20 to 30% leads to the creation of dominating molybdates. This leads to a concomitant drop in the number of formed ZnO nanorods.
8 August 2025 in Journal of Applied Crystallography
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