Studying the ecosystem service value is of great value for solving the contradiction between ecological protection and economic development in the Huaihe River Basin. The characteristics of land use change were studied by using the Landsat remote sensing image data of Anhui section and Henan section of Huaihe River Basin from 2010 to 2020. The equivalent factor method was used to estimate the ecosystem service value, and the spatial autocorrelation model was used to analyze the spatial distribution characteristics of ecosystem service value The GM-BP model was used to predict the land use change in 2025. The results showed that: (1) From 2010 to 2020, cultivated land and construction land dominated the land use in the study area, and the degree of land use change changed from severe to stable. (2) The value of ecosystem services is in the transition stage from low level (II) to medium level (III). (3) ecosystem service value has a significant positive spatial correlation, and the spatial distribution is generally high in the southeast and low in the northwest. (4) Compared with 2020, ecosystem service value will rise by 0.54 % in 2025.
Membrane technology demonstrates broad prospects in the field of methane capture and purification due to its high efficiency and low energy consumption characteristics. This paper systematically reviews the research progress in membrane technology for methane separation in recent years, focusing on the design and optimization of membrane material systems, in-depth analysis of mass transfer mechanisms, and practical applications in areas such as biogas upgrading and natural gas decarbonization. Researchers have significantly enhanced membrane separation performance for CO2/CH4, CH4/N2, and other systems by developing novel material systems such as polymer membranes, inorganic membranes, and mixed matrix membranes (MMMs), combined with strategies like pore structure regulation, interface optimization, and functionalization. Although membrane technology has shown good economic feasibility and application potential in some scenarios, challenges such as long-term material stability, anti-plasticization capability, and large-scale manufacturing remain the main current obstacles. Future research should further focus on the development of novel membrane materials, process integration optimization, and intelligent process control to promote a greater role for membrane technology in the efficient utilization of methane resources and energy structure transformation.