The long ring pommel Dao (a kind of single-edged blade), a significant indigenous Chinese weaponry innovation of the Western Han Dynasty, is researched this study. Employing a comparative research methodology, we conduct a scientific analysis of samples excavated from the tombs of marquisates across various regions of China, spanning from the northern to the southern extremities. This analysis encompasses metallographic examination, inclusion composition analysis, and scanning electron microscopy (SEM), complemented by the application of a metallurgical kinetic model to reconstruct key smelting operations. The semifinished materials of the long ring pommel Dao are sourced from two primary origins: bloomery carburized steel and cast iron-puddling joint decarburization steel (cast iron-Chaogang steel). Both pathways exhibit a predominance of FeOx·SiO2y oxide inclusions. Our investigation particularly emphasizes the Fe2SiO4 inclusions, which have a melting point of 1178℃. By leveraging the length/width ratio of Fe2SiO4 inclusions, we can ascertain whether the smelting process involved an all-liquid phase. Notably, the length/width ratio of Fe2SiO4 inclusions in the cast iron-puddling joint process exceeded 5. Additionally, our findings reveal that during the cast iron-puddling joint decarburization process, when the forging temperature falls below 880℃, the mesh-like Fe2SiO4 inclusions undergo fragmentation. This phenomenon provides crucial insights into the forging system of the Han Dynasty, facilitating a more detailed reconstruction of its metallurgical practices.
5 November 2022 in Journal of Archaeological Science: Reports
The study of co-fusion was one of the essential topics in the history of metallurgy in China. Simulation experiments were an essential concept in the study of the co-fusion steelmaking process. This paper mainly studied the simulation experiments of co-fusion from two aspects: the replication of co-fusion swords by three different methods and the micro-analysis of the co-fusion samples. The experimental results indicated that several co-fusion swords could be made by different processes, but the carbon content and surface hardness were quite different. During repeated forge welding, the microstructure of the samples transformed from laminated to homogenized; finally, a steel with a uniform carbon content was obtained. It was challenging to determine the characteristics of co-fusion from the homogenized samples. The results prompt a rethinking of the microstructural characteristics of ancient co-fusion artifacts.
Wenzhou Alum Mine in Fanshan Town, Zhejiang Province (China), operated from the middle of the 14th century to December 2017 and, as an important centre of the Chinese alum industry for more than 600 years, witnessed both change and continuity in the development of alum mining and refining technology. Alum was produced in Wenzhou from the alunite ore mined in the territory, and included quarrying, calcining, weathering and steeping the ore to produce an impure solution, or liquor, of aluminium sulphate and potassium sulphate, which was then boiled at the appropriate temperature to form a concentration of alum. A review of the documentary evidence coupled with an archaeological survey of the mining and refining sites owned by the Wenzhou Alum Mine Company has enabled the site to be redefined as a complex production landscape by paying attention to the evidence for the evolution of technology used for producing alum.