University of Texas at San Antonio, Chemical Engineering Program – Department of Biomedical Engineering, Department of Mechanical Engineering, One UTSA Circle, San Antonio, TX 78249, USA
Dr. Gary Jacobs
University of Texas at San Antonio, Chemical Engineering Program – Department of Biomedical Engineering, Department of Mechanical Engineering, One UTSA Circle, San Antonio, TX 78249, USA
Cleaning Diesel Exhaust: One strategy for removing pollutants from diesel engine exhaust is to trap the unburned carbon soot and then to combust the soot with the NO 2 that is generated from NO; the two pollutants are then converted to N 2 and CO 2 . Diesel exhaust is relatively cold, compared to gasoline engine exhaust, and conversion of NO to NO 2 has required the use of platinum catalysts.
W. Wang
et al. (p. 832 ) now report that a more earth-abundant catalyst, based on Mn-mullite (Sm, Gd)Mn 2 O 5 metal oxides was able to oxidize NO in simulated diesel exhaust at temperatures as low as 75°C. Spectroscopic studies and quantum chemical modeling suggested that Mn-nitrates formed on Mn-Mn dimer sites were the key intermediates responsible for NO 2 formation.