Wood-derived carbon has a 3D porous framework composed of through channels along the growth direction, which is a suitable matrix for preparing electromagnetic wave (EMW) absorbing materials with low cost, light weight, and environmental friendliness. Herein, the carbonized wood decorated by short cone-like NiCo₂O₄ (NiCo₂O₄@CW) with highly ordered straight-channel architecture was successfully manufactured through a facile calcination procedure. The horizontal arrangement of the through channels of NiCo₂O₄@CW (H-NiCo₂O₄@CW) exhibits a strong reflection loss value of -64.0 dB at 10.72 GHz with a thickness of 3.62 mm and a low filling ratio of 26 wt% (with the density of 0.98 g·cm^-3), and the effective absorption bandwidth (EAB) is 8.08 GHz (9.92–18.0 GHz) at the thickness of 3.2 mm. The excellent microwave absorption (MA) property was ascribed to the ordered-channel structure with abundant interfaces and defects from NiCo₂O₄@CW, which could promote the interfacial polarization and dipole polarization. What is more, this advantageous structure increased the multiple reflections and scattering. Finite element analysis (FEA) simulation is carried out to detect the interaction between the prepared material and EMW when the ordered channels are arranged in different directions. This research provides a low-cost, sustainable, and environmentally friendly strategy for using carbonized wood to fabricate microwave absorbers with strong attenuation capabilities and light weight.

Carbon nanofibers decorated with porous carbon nanotubes were prepared by electrospinning and annealing methods. The microwave reflection loss of the products was investigated in the frequency range of 2–18 GHz. The bandwidth with a reflection loss less than −10 dB covers a wide frequency, ranging from 7.0 to 14.1 GHz with thickness of 3.0–5.5 mm, and the minimum reflection loss is −44.5 dB at 10.7 GHz with thickness of 2.0 mm. The large reflection loss and wide reflection band reveal that the products could be a promising candidate for microwave absorption.