Harmonious developments of electrical and mechanical performances are crucial for stretchable sensors in structural health monitoring (SHM) of flexible aircraft such as aerostats and morphing aircrafts. In this study, we prepared a highly durable ternary conductive nanocomposite made of polydimethylsiloxane (PDMS), carbon black (CB) and multi-walled carbon nanotubes (MWCNTs) to fabricate stretchable strain sensors. The nanocomposite has excellent electrical and mechanical properties by intensively optimizing the weight percentage of conducting fillers as well as the ratio of PDMS pre-polymer and curing agent. It was found that the nanocomposite with homogeneous hybrid filler of 1.75 wt % CB and 3 wt % MWCNTs exhibits a highly strain sensitive characteristics of good linearity, high gauge factor (GF ~ 12.25) and excellent durability over 10⁵ stretching-releasing cycles under a tensile strain up to 25% when the PDMS was prepared at the ratio of 12.5:1. A strain measurement of crack detection for the aerostats surface was also employed, demonstrating a great potential of such ternary nanocomposite used as stretchable strain sensor in SHM.

Large, 3D curved electronics are a trend of the microelectronic industry due to their unique ability to conformally coexist with complex surfaces while retaining the electronic functions of 2D planar integrated circuit technologies. However, these curved electronics present great challenges to the fabrication processes. Here, we propose a reconfigurable, mask-free, conformal fabrication strategy with a robot-like system, called robotized ‘transfer-and-jet’ printing, to assemble diverse electronic devices on complex surfaces. This novel method is a ground-breaking advance with the unique capability to integrate rigid chips, flexible electronics, and conformal circuits on complex surfaces. Critically, each process, including transfer printing, inkjet printing, and plasma treating, are mask-free, digitalized, and programmable. The robotization techniques, including measurement, surface reconstruction and localization, and path programming, break through the fundamental constraints of 2D planar microfabrication in the context of geometric shape and size. The transfer printing begins with the laser lift-off of rigid chips or flexible electronics from donor substrates, which are then transferred onto a curved surface via a dexterous robotic palm. Then the robotic electrohydrodynamic printing directly writes submicrometer structures on the curved surface. Their permutation and combination allow versatile conformal microfabrication. Finally, robotized hybrid printing is utilized to successfully fabricate a conformal heater and antenna on a spherical surface and a flexible smart sensing skin on a winged model, where the curved circuit, flexible capacitive and piezoelectric sensor arrays, and rigid digital–analog conversion chips are assembled. Robotized hybrid printing is an innovative printing technology, enabling additive, noncontact and digital microfabrication for 3D curved electronics.

Seamless integration of microstructures and circuits on three-dimensional (3D) complex surfaces is of significance and is catalyzing the emergence of many innovative 3D curvy electronic devices. However, patterning fine features on arbitrary 3D targets remains challenging. Here, we propose a facile charge-driven electrohydrodynamic 3D microprinting technique that allows micron- and even submicron-scale patterning of functional inks on a couple of 3D-shaped dielectrics via an atmospheric-pressure cold plasma jet. Relying on the transient charging of exposed sites arising from the weakly ionized gas jet, the specified charge is programmably deposited onto the surface as a virtual electrode with spatial and time spans of ~mm in diameter and ~μs in duration to generate a localized electric field accordantly. Therefore, inks with a wide range of viscosities can be directly drawn out from micro-orifices and deposited on both two-dimensional (2D) planar and 3D curved surfaces with a curvature radius down to ~1 mm and even on the inner wall of narrow cavities via localized electrostatic attraction, exhibiting a printing resolution of ~450 nm. In addition, several conformal electronic devices were successfully printed on 3D dielectric objects. Self-aligned 3D microprinting, with stacking layers up to 1400, is also achieved due to the electrified surfaces. This microplasma-induced printing technique exhibits great advantages such as ultrahigh resolution, excellent compatibility of inks and substrates, antigravity droplet dispersion, and omnidirectional printing on 3D freeform surfaces. It could provide a promising solution for intimately fabricating electronic devices on arbitrary 3D surfaces.

When a charge neutral drop impacts on a flat solid substrate, a small air bubble is always trapped underneath due to the lubrication pressure coming from the viscous stress in the squeezed air film. Herein we find experimentally and numerically that the process of the air entrapment and the initial contact state of the drop with the substrate can be profoundly altered via an external electric field. In an electric field, the induced electric stresses at the bottom of the drop increase drastically right before the drop contacts the substrate, which acts against the lubrication pressure, resulting in reduced initial contact radius and air bubble size. When the external electric field reaches a critical value, the electrical stress accelerates the flow near the bottom of the drop and generates a conical tip quickly instead of a dimple, resulting in a centre contact and eliminating the air bubble entrapment. Based on the dipole mirror charge model, we find the dimensionless strength of critical electric field scales with the square root of capillary number based on the air viscosity. This scaling law of the critical electric field for eliminating the air bubble entrapment is verified experimentally and numerically. This work may offer a new way to mitigate defects caused by air bubble entrapment for inkjet printing and droplet-based additive manufacturing.

Depositing drops on a solid surface without entrapping bubbles is desirable for many spray coating and printing applications. Tian et al. [ J. Fluid Mech. 946, A21 (2022)] reported that an electric field can be applied to eliminate air bubble entrapments for neutral drops. Herein we provide a complete physical picture of the entire process of a drop impacting onto the solid surface under an external electric field. The electrohydrodynamic behavior during the drop impact is divided into three stages: the deformation of the drop in the electric field prior to contact, the initial contact of the drop with the substrate, and the rich postcontact phenomena including spreading, receding, jetting, and fragmentation. The results show that under the increasingly stronger electric fields, the modest drop oscillation transforms into a vertically stretched spindle. As the drop approaches the substrate, the electric stress at the south pole increases rapidly, which sharpens the bottom surface into a conical shape. The cone angle is determined by both the impact velocity and the electric field strength. After the contact, the surface electric stress tends to pull the drop upward, breaking up the drop, forming several jetting modes, and reducing the maximum spreading radius. The various drop deposition modes are summarized in a phase diagram, which sheds light on identifying appropriate electric fields for high-quality drop depositions without air bubble entrapments or jettings.