Ferromagnetism in 2D materials has attracted tremendous interest from the scientific community thanks to its potential for the design of magnetic materials with unique properties. The presence of a ferromagnetic element in a 2D material can improve the existing properties and offer new ones, giving rise to the development of manifold applications. This review focuses on recent advances and perspectives of 2D materials that bear at least one ferromagnetic element (iron, cobalt, nickel) as i) structural constituent, ii) dopant atom, or iii) adjacent atom through proximity effect. By describing in detail the magnetic properties that have emerged so far, their potential to form next‐generation 2D magnets is discussed. Moreover, the contribution of such 2D materials is analyzed in various applications (electrochemical, photochemical, optical, and electronic), aiming to explore further functionalities and capabilities of ferromagnetic elements, apart from their magnetic nature. Special attention is given to gadolinium and other rare earth elements that display a ferromagnetic order even at ultra‐low temperatures and form part of 2D structured materials, with particularly appealing properties deriving from their 4f electrons.

Magnetism in two-dimensional materials reveals phenomena distinct from bulk magnetic crystals, with sensitivity to charge doping and electric fields in monolayer and bilayer van der Waals magnet CrI₃. Within the class of layered magnets, semiconducting CrSBr stands out by featuring stability under ambient conditions, correlating excitons with magnetic order and thus providing strong magnon-exciton coupling, and exhibiting peculiar magneto-optics of exciton-polaritons. Here, we demonstrate that both exciton and magnetic transitions in bilayer and trilayer CrSBr are sensitive to voltage-controlled field-effect charging, exhibiting bound exciton-charge complexes and doping-induced metamagnetic transitions. Moreover, we demonstrate how these unique properties enable optical probes of local magnetic order, visualizing magnetic domains of competing phases across metamagnetic transitions induced by magnetic field or electrostatic doping. Our work identifies few-layer CrSBr as a rich platform for exploring collaborative effects of charge, optical excitations, and magnetism.

In monolayer transition metal dichalcogenides, time-reversal symmetry—combined with broken space-inversion symmetry—defines the spin–valley degree of freedom. As such, the engineering and control of time-reversal symmetry by optical or magnetic fields constitutes the foundation of valleytronics. Here we propose a new approach for the detection of broken time-reversal symmetry and valley imbalance in monolayer WSe₂ based on second-harmonic generation. At room temperature, our method can selectively probe a net valley imbalance generated by ultrafast, coherent and valley-exclusive optical Stark and Bloch–Siegert effects. This work demonstrates the potential and unique capabilities of nonlinear optics as a probe of broken time-reversal symmetry as well as a tool for ultrafast and non-destructive valleytronic operations.

Commercially available conductive filaments are not designed for electrochemical applications, resulting in 3D printed electrodes with poor electrochemical behavior, restricting their implementation in energy and sensing technologies. The proper selection of an activation method can unlock their use in advanced applications. In this work, rectangular electrodes made from carbon black – polylactic acid (CB/PLA) filament are 3D printed with different layouts (grid and compact) and then activated using a highly reproducible eco‐compatible electrochemical (EC) treatment. The electrodes are characterized for their morphological, structural, and electrochemical features to obtain insights into the material properties and functionality. Furthermore, the influence of the electrode layout as well as the activation conditions are studied aiming to provide a better understanding of the mechanism driving the electrochemical behavior of the electrodes. The EC activation enhances the electrochemical performance, provides a uniform electrochemical activity in the electrode's interface and allows the manipulation of the electrochemical properties of 3D printed electrodes by adjusting the duration of the treatment. CB/PLA electrodes offer a wide stable potential window that benefits their use in water‐based electrochemical applications. Thus, their suitability for Zn‐ion batteries and electrochemical sensing is explored, followed by their application in hydroquinone determination in water samples.