Over the years, different types of alternative technologies have been developed and used for palm oil mill effluent (POME) treatment. Specifically, membrane bioreactor (MBR) has been employed to relegate pollutants contained in POME under different operating conditions, and the technology was found to be promising. The major challenge impeding the wider application of this technology is membrane fouling, which usually attracts high operating energy and running cost. In this regard, novel methods of mitigating membrane fouling through the treatment processes have been developed. Therefore, this review article specifically focuses on the recent treatment processes of POME using MBR, with particular emphasis on innovative processes conditions such as aerobic, anaerobic, and hybrid processing as well as their performance in relation to fouling minimization. Furthermore, the effects of sonication and thermophilic and mesophilic conditions on membrane blockage were critically reviewed. The types of foulants and fouling mechanism as influenced by different operating conditions were also analyzed censoriously.

High proportion of copper has become a global challenge owing to its negative impact on the environment and public health complications. The present study focuses on the fabrication of a polyvinylidene fluoride (PVDF)-polyvinyl pyrrolidone (PVP) fiber membrane incorporated with varying loading (0, 0.5, 1.0, 1.5, and 2.0 wt%) of titanium dioxide (TiO₂) nanoparticles via phase inversion technique to achieve hydrophilicity along with high selectivity for copper removal. The developed fibers were characterized based on scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), permeability, porosity, zeta potential, and contact angle. The improved membrane (with 1.0 wt% TiO₂) concentration recorded the maximum flux (223 L/m²·h) and copper rejection (98.18%). Similarly, 1.0 wt% concentration of TiO₂ nanoparticles made the membrane matrix more hydrophilic with the least contact angle of 50.01°. The maximum copper adsorption capacity of 69.68 mg/g was attained at 1.0 wt% TiO₂ concentration. The experimental data of adsorption capacity were best fitted to the Freundlich isotherm model with R² value of 0.99573. The hybrid membrane developed in this study has considerably eliminated copper from leachate and the concentration of copper in the permeate was substantially reduced to 0.044 mg/L, which is below standard discharge threshold.

This study focused on developing a hydrophilic hybrid polyvinylidene fluoride (PVDF)-polyethylene glycol (PEG) hollow membrane by incorporating Nano-magnesium oxide (NMO) as a potent antifouling mediator. The Nano-hybrid hollow fibers with varied loading of NMO (0 g; 0.25 g; 0.50 g; 0.75 g and 1.25 g) were spun through phase inversion technique. The resultants Nano-hybrid fibers were characterized and compared based on SEM, EDX, contact angle, surface zeta-potential, permeability flux, fouling resistance and color rejection from palm oil mill effluent (POME). Noticeably, the permeability flux, fouling resistance and color rejection improved with the increase in NMO loading. PVDF-PEG with 0.50 g-NMO loading displayed an outstanding performance with 198.35 L/m²·h, 61.33 L/m²·h and 74.65% of water flux, POME flux and color rejection from POME, respectively. More so, a remarkable fouling resistance were obtained such that the flux recovery, reversible fouling percentage and irreversible fouling percentage remains relatively steady at 90.98%, 61.39% and 7.68%, respectively, even after 3 cycles of continuous filtrations for a total period of 9 h. However, at excess loading of 0.75 and 1.25 g-NMO, deterioration in the flux and fouling resistance was observed. This was due to the agglomeration of nanoparticles within the matrix structure at the excessive loading.

The present study synthesized nano-magnetite (Fe₃O₄) from milled steel chips using the high energy ball milling (HEBM) method, characterized it, and then utilized it as a sorbent to remediate boron concentration at various pH (4–9), dosages (0.1–0.5 g), contact times (20–240 min), and initial concentrations (10–100 mg/L). The nano-sorbents were characterized based on SEM structure, elemental composition (EDX), surface area analysis (BET), crystallinity (XRD), and functional group analysis (FTIR). The highest adsorption capacity of 8.44 mg/g with removal efficiency of 84% was attained at pH 8, 0.5 g dosage, contact time of 180 min, and 50 mg/L initial concentration. The experimental data fit best with the pseudo-second-order kinetic model with R² of 0.998, while the Freundlich adsorption isotherm describes the adsorption process with an R² value of 0.9464. A regeneration efficiency of 47% was attained even after five cycles of reusability studies. This efficiency implies that the nano-magnetite has the potential for sustainable industrial application.