The exploitation of groundwater in arid and semi-arid areas, especially in basins where groundwater is intensively exploited, is likely to have adverse effects on the originally fragile ecological environment, which also greatly alter the hydrogeochemical evolution process. Over-abstraction of groundwater in the Haolebaoji watershed of the Ordos Basin located in the semi-arid regions has led to a series of changes in the groundwater system, which has attracted considerable attention from environmental protection organizations. However, the origin and geochemical evolution of groundwater in the Haolebaoji watershed have not been revealed. In this study, the Haolebaoji watershed is selected as the typical study area to investigate hydrogeochemical evolution under the intensive groundwater exploitation. Groundwater samples were collected and tested for major ions and stable isotopes (δ¹⁸O, δD). Various approaches including the ion proportional relationship diagram, chlor-alkali index, saturation index, Gibbs diagram, and principal factor analysis were used to reveal the hydrogeochemical processes regulating the groundwater geochemistry. The groundwater in the study area is divided into five hydrochemical types according to the Piper diagram. It was found that the chemical composition of groundwater in the study area is mainly controlled by the dissolution of calcite, dolomite, gypsum, and halite. The cation exchange intensity gradually increased with the flow of groundwater from the recharge to the discharge area. Rock weathering plays a controlling role in the formation of groundwater geochemistry, but it is also controlled by evaporative crystallization in some runoff and discharge areas. Groundwater is predominantly recharged by modern local atmospheric precipitation, and deep wells receive water supply during cold periods. The study findings provide important information for the development of sustainable groundwater management strategies for the Ordos Energy Base.

《地球科学》(ISSN 1000-2383;CN42-1874/P) (原刊名《地球科学——中国地质大学学报》ISSN 1000-2383;CN42-1233/P)，创刊于1957年，是由教育部主管、中国地质大学主办的综合性地学学术理论期刊，月刊，2015年改名为《地球科学》,她以反映中国地质大学教学与科研最新的、高水平的基础地质、应用地质、资源与环境地质及地学工程技术研究成果为主要任务。

Accurate quantification of groundwater evapotranspiration (ET_g) is essential for reliable water resource assessment. Existing methods for estimating ET_g from water table fluctuation largely rely on one-dimensional simplifications that neglect transient groundwater flow. However, in areas with shallow water table and topographic relief, where transient groundwater flow often occurs, the validity and accuracy of this simplification remain inadequately evaluated. In this study, we used HYDRUS-2D to construct a 50 m-long sandy hillslope with a 0.05 gradient to investigate ET_g based on the water table fluctuation (WTF) method under transient groundwater flow conditions. The results indicate that periodic evapotranspiration generates water table fluctuations along the hillslope that exhibit amplitude attenuation and temporal phase lag, features not captured by 1D models. Ignoring transient groundwater flow leads to a systematic underestimation of ET_g by up to 85% in sandy soil near the topographic lows. Furthermore, we found that both the decoupling depth and the extinction depth are significantly amplified by lateral groundwater flow, by up to 66% and 51%, respectively, compared with 1D estimates derived from the Shah method. These findings highlight the importance of incorporating transient flow processes into ET_g estimation to improve the accuracy of water balance assessments and ecohydrological predictions, particularly in areas with shallow water tables and topographic relief.