We present a new global survey of the purest anorthosite (PAN) rock using the Spectral Profiler onboard Kaguya. We found that PAN rocks are widely distributed over the Moon, including the Feldspathic Highland Terrain and the south and north polar regions. All PAN sites are associated with huge impact structures with diameters larger than 100 km. Based on the global distributions of PAN and olivine‐rich sites, we propose the existence of a massive PAN layer with a thickness of ∼50 km below an uppermost mafic‐rich mixed layer with a thickness of ∼10 km. Below the PAN layer, a lower crustal layer with olivine‐rich materials may be present on the nearside, but not on the far side of the Moon. The existence of a PAN layer with a thickness of ∼50 km suggests an Al₂O₃ abundance of 33 to 34 wt.% in the lunar crust, which is higher than previous estimates of <32 wt.%. Our data indicate the massive production event of PAN during the early stage of the formation of the Moon, supporting the lunar magma ocean scenario.