Pt/nanostructured molybdenum oxide Schottky diode based gas sensors were fabricated for hydrogen gas sensing. Due to the enhanced performance, which is ascribed to the application of nanostructures, these devices were used in reversed bias. characterization by scanning electron microscopy showed morphology of randomly orientated nanoplatelets with thicknesses between 50 and 500 nm. An mixed phase crystallographic structure of was characterized by x-ray diffraction. At , 1.343 V voltage shift in the reverse curve and a barrier height change of 20 meV were obtained after exposure to 1% gas in synthetic air.