The significant increase in lithium batteries consumption produces a significant quantity of discarded lithium-ion batteries (LIBs). On the one hand, the shortage of high-grade ores leads to the necessity of processing low-grade ores, which contain a low percentage of valuable metals in comparison to the discarded LIBs that contain a high percentage of these metals, which enhances the processing of the discarded LIBs. On the other hand, the processing of discarded LIBs reduces the negative environmental effects that result from their storage and the harmful elements contained in their composition. Hence, the current study aims at developing cost-effective and ecofriendly technology for cobalt and lithium metal ion recovery based on discarded LIBs. A novel synthesized solid-phase adsorbent (TZAB) was utilized for the selective removal of cobalt from synthetic solutions and spent LIBs. The synthesized TZAB adsorbent was characterized by using 13C-NMR, GC-MS, FT-IR, 1H-NMR, and TGA. The factors affecting the adsorption of cobalt and lithium ions from synthetic solutions and spent LIBs, including the sorbent dose, pH, contact time, temperature, and cobalt concentration were investigated. The conditions surrounding the recovery of cobalt and lithium from processing discarded LIBs, were investigated to optimize the maximum recovery. The Langmuir, Freundlich, and Dubinin–Radushkevich (D-R) isotherm models were used to study the kinetics of the adsorption process. The obtained results showed that high-purity CoC₂O₄ and Li₃PO₄ were obtained with a purity of 95% and 98.3% and a percent recovery of 93.48% and 95.76%, respectively. The maximum recovery of Co(II) from synthetic solutions was obtained at C₀ = 500 mg·L⁻¹, dose of 0.08 g, pH 7.5, T = 25 °C, and reaction time = 90 min. The collected data from Langmuir’s isotherm and the adsorption processes of Co agree with the data predicted by the D-R isotherm models, which shows that the adsorption of Co(II) onto the TZAB seems to be chemisorption, and the results agree with the Langmuir and D-R isotherm models.

A spiral concentrator is a gravity concentration device. It was invented by Humphreys in 1941. Firstly, it was designed and developed based on experience and by extensive testing of prototypes and modifications. The main objective of the present study is the simulation of the particulate flow of more realistic solid concentrations (i. e., 15 wt.-% solids) in a spiral separator. This study is based on the Eulerian approach and renormalization group k-∊ turbulence modeling. The results focus on particulate flow characteristics such as velocity, distribution and concentration of particulates on the spiral trough. The predicted results were compared with the experimental results in case of LD9 coal spiral. Comparisons between numerical and measured data showed good agreement.