The present paper reviews recent advances on the direct synthesis of 5-hydroxymethylfurfural (HMF) from different kinds of raw biomasses. In particular, in the paper HMF production from: (i) edible biomasses; (ii) non-edible lignocellulosic biomasses; (iii) food wastes (FW) have been reviewed. The different processes and catalytic systems have been reviewed and their merits, demerits and requirements for commercialisation outlined.

Catalytic conversion of actual biomass to valuable chemicals is a crucial issue in green chemistry. This review discusses on the recent approach in the levulinic acid (LA) formation from three prominent generations of biomasses. Our paper highlights the impact of the nature of different types of biomass and their complex structure and impurities, different groups of catalyst, solvents, and reaction system, and condition and all related pros and cons for this process.

The reaction between hydrogen and oxygen is in principle the simplest method to form hydrogen peroxide, but it is still a “dream process”, thus needing a “dream catalyst”. The aim of this review is to analyze critically the different heterogeneous catalysts used for the direct synthesis of H₂O₂ trying to determine the features that the ideal or “dream catalyst” should possess. This analysis will refer specifically to the following points: (i) the choice of the metal; (ii) the metal promoters used to improve the activity and/or the selectivity; (iii) the role of different supports and their acidic properties; (iv) the addition of halide promoters to inhibit undesired side reactions; (v) the addition of other promoters; (vi) the effects of particle morphology; and (vii) the effects of different synthetic methods on catalyst morphology and performance.

The use of carbon dioxide, the most concerning environmental issue of the 21st century, as a feedstock for fuels productions still represents an innovative, yet challenging, task for the scientific community. CO₂ photoreduction processes have the potential to transform this hazardous pollutant into important products for the energy industry (e.g., methane and methanol) employing a photocatalyst and light as the only energy input. In order to design an effective process, the high sustainability of this reaction should be matched with the perfect reaction conditions to allow the reactant, photocatalyst, and light source to come together: therefore, the choice of reaction conditions, and in particular its medium, is a crucial issue that needs to be investigated. Throughout this paper, a careful study of carbon dioxide photoreduction in liquid and vapour phases are reported, focusing on their effect on catalyst performances in terms of light harvesting, productivity, and selectivity. Different from most papers in the literature, catalytic tests were performed under extremely low light irradiance, in order to minimise the primary energy input, highlighting that this experimental variable has a great effect on the reaction pathway and, thus, product distribution.