In this work, in situ polymerization of modified sol-gel silica in a polyether sulfone matrix is presented to control the interfacial defects in organic-inorganic composite membranes. Polyether sulfone polymer and modified silica are used as organic and inorganic components of mixed matrix membranes (MMM). The membranes were prepared with different loadings (2, 4, 6, and 8 wt.%) of modified and unmodified silica. The synthesized membranes were characterized using Field emission electron scanning microscopy, energy dispersive X-ray, Fourier transform infrared spectroscopy, thermogravimetric analyzer, and differential scanning calorimetry. The performance of the membranes was evaluated using a permeation cell set up at a relatively higher-pressure range (5–30 bar). The membranes appear to display ideal morphology with uniform distribution of particles, defect-free structure, and absence of interfacial defects such as voids and particle accumulations. Additionally, the CO₂/CH₄ selectivity of the membrane increased with the increase in the modified silica content. Further comparison of the performance indicates that PES/modified silica MMMs show a promising feature of commercially attractive membranes. Therefore, tailoring the interfacial morphology of the membrane results in enhanced properties and improved CO₂ separation performance.

Sustainable fertilizer technologies are essential to address nutrient losses, environmental pollution, and inefficiencies associated with conventional urea application. In this study, humic acid–functionalized starch (St–HA) gel coatings were developed and optimized via a Wurster fluidized-bed system to produce controlled-release urea granules, with an additional carnauba wax outer layer to further extend nutrient release duration. The coating formulation was synthesized through in situ crosslinking of tapioca starch with humic acid using N,N′-methylenebisacrylamide and potassium persulfate, yielding a cohesive film. A central composite rotatable design (CCRD) was employed to investigate the influence of atomizing air pressure, fluidizing air flow rate, fluidized-bed temperature, and spray rate on coating performance. Comprehensive characterization; including FTIR, XRD, rheological analysis, thermogravimetric studies, water retention, biodegradability, and surface abrasion, confirmed chemical crosslinking, structural stability, and mechanical robustness of the coatings. Nitrogen release analysis in both water and soil demonstrated a substantial extension of release longevity from less than 2 days (uncoated) to 18–20 days for St–HA-coated urea, and up to 28 days with the additional wax coating. Coated granules exhibited low abrasion (8–24%), high water-retention capacity, and 68% biodegradation in 60 days, ensuring environmental compatibility. The findings establish St–HA/wax hybrid coatings as a viable, eco-friendly strategy for controlled-release fertilizers, integrating renewable feedstocks with scalable industrial processing for precision nutrient management.

The quantification of damage, in plates, pipes and such like structures, is one of the current research areas. In this study, to estimate the notch size, shape, and orientation was carried out experimentally based on fundamental shear horizontal mode, SH0 mode. Using least number of transmitters, the reconstruction algorithm for the probabilistic inspection of damage (RAPID) has been used to carry out fast and efficient investigation of scattered waves using SH0 wave interaction with notch at various incident angles. An approach of ultrasonic guided waves and (RAPID) algorithm, using a direction-tunable shear-horizontal mode array magnetostrictive patch transducer (DT-SHMA-MPT), the notch in a thin aluminum plate is experimented. Firstly, the RAPID algorithm, based on SH0 mode, is used here to quantitatively study a notch in a thin aluminium plate. Secondly, the imaging application using DT-SHMA-MPT is achieved. Experiments were conducted using an array of eight DT-SHMA-MPTs based on a pitch-catch mode to utilize the scattered waves at the notch. The results obtained through experiments reveal the effect of directionality of the scattered waves and have find out the optimal transducers configuration. The localization, quantification and orientation at the same time are obtained using only two or three transmitters. To improve the accuracy of imaging, a threshold value was selected. The presented approach can be used to detect, locate and image the surface defects in aluminum plate.