The presence of excessive amounts of nutrients including phosphates in water is undesirable. They cause the deterioration of water quality and problems in many natural and engineering systems. The recycling of agricultural waste materials as biosorbents for contaminants removal provides a cheap and ecological means to reduce wastes. This study explored the use of date palm wastes for the effective removal of phosphate from aqueous solutions. Granular date stones (GDS) and palm surface fibres (PSF) as raw abundant waste materials were examined for PO₄ ^-3 removal from aqueous solution. The experimental work was performed in a batch mode to investigate the influence of initial phosphate concentration, contact time, and pH of solution on phosphate biosorption. The FT-IR spectra for the waste materials display many adsorption peaks, confirming the complex nature of the GDS and PSF. Phosphate percentage removal up to 87 and 85% were obtained at initial PO₄ ^-3 concentration of 50 mg as P/L using GDS and PSF, respectively. Due to their low cost and high capability, these types of waste can be used for cost-effective removal of phosphate from wastewater.

Microbial fuel cells (MFCs) have the potential to simultaneously treat wastewater for reuse and to generate electricity. This study mainly considers the performance of an upflow dual‐chambered MFC continuously fueled with actual domestic wastewater and alternatively biocatalyzed with aerobic activated sludge and strain of Bacillus Subtilis. The behavior of MFCs during initial biofilm growth and characterization of anodic biofilm were studied. After 45 days of continuous operation, the biofilms on the anodic electrode were well developed. The performance of MFCs was mainly evaluated in terms of COD reductions and electrical power output. Results revealed that the COD removal efficiency was 84% and 90% and the stabilized power outputs were clearly observed achieving a maximum value of 120 and 270 mW/m² obtained for MFCs inoculated with mixed cultures and Bacillus Subtilis strain, respectively.

In this study, the application of immobilized mixed cells for decolorization, biodegradation, and detoxification of reactive yellow dye (RY15) in textile wastewater was investigated via a sequential anaerobic-aerobic process in bench-scale bioreactors and lab-scale bioreactors as well. The mixed cultures were immobilized using three different biocarriers which were sodium alginate (SA), starch (St), and Gelatin (Ge), by the cross-linking with polyvinyl alcohol (PVA). Results revealed that the immobilized cultures had a potential degrading efficiency in the anaerobic and aerobic environment, targeting the initial structure and the formed compounds, respectively. Complete decolorization (100%) of RY15 was observed with a significant COD removal, which enhanced the subsequent aerobic phase. Results demonstrated that COD removals were 92% ± 6.8, 96% ±3.5, and 100%, using PVA-SA, PVA-St, and PVA-Ge at RY15 initial concentrations of 10 mg/L, respectively. The experimental work was extended to investigate the dye biodegradation in real textile wastewater (TWW) using mixed cells in immobilized in PVA-SA. The OLR and HRT of the aerobic bioreactor are 24.5 mg/L.h ${\displaystyle \frac{\mathrm{m}\mathrm{g}}{\mathrm{L}.\mathrm{h}}\frac{\mathrm{m}\mathrm{g}}{\mathrm{L}.\mathrm{h}}}$ and 41.37 h, respectively. The experimental profiles of RY concentration, COD reduction along with biomass growth, were in good agreement with the model predicted profiles. The effectiveness factors were 0.96 and 0.99 for the anaerobic and aerobic phases, respectively.