Accurate prediction of the air quality index (AQI) is crucial for understanding urban pollution dynamics and protecting public health. This study proposes a dual-branch fusion framework (CL-XGB-Season) to address seasonal heterogeneity in AQI prediction by integrating temporal dynamic features and static patterns. The CNN-LSTM branch captures short-term temporal fluctuations, while a seasonally split XGBoost branch fits long-term static patterns via independent submodels for spring, summer, autumn, and winter. SHAP-based interpretability analysis revealed the dominant drivers across different seasons: the “temperature × O₃” interaction feature plays a key role in summer, characterizing the ozone formation mechanism dominated by photochemical reactions under conditions of high temperature and strong solar radiation; whereas the PM_2.5/PM₁₀ ratio is crucial in winter (where pollution is primarily driven by pollutant accumulation). The dual-branch fusion framework was validated using hourly resolution data from Chongqing for the 2020–2025 period. Results indicate that the framework achieved a prediction accuracy of 0.197 root mean square error (nRMSE) and 0.9611 coefficient of determination (R²) on the test set, outperforming eight ablation variants and five baseline models (ARIMA, Transformer, etc.) in comparative experiments. Ablation studies confirm the necessity of dual branches and seasonal modeling, with the full model reducing nRMSE by 19–63% versus single-model variants. This framework maintains stable seasonal performance and provides actionable insights for targeted air quality management.