The removal of ethane (C₂H₆) from its analogous ethylene (C₂H₄) is of paramount importance in the petrochemical industry, but highly challenging due to their similar physicochemical properties. The use of emerging porous organic cage (POC) materials for C₂H₆/C₂H₄ separation is still in its infancy. Here, we report the benchmark example of a truncated octahedral calix[4]resorcinarene-based POC adsorbent (CPOC-301), preferring to adsorb C₂H₆ than C₂H₄, and thus can be used as a robust absorbent to directly separate high-purity C₂H₄ from the C₂H₆/C₂H₄ mixture. Molecular modelling studies suggest the exceptional C₂H₆ selectivity is due to the suitable resorcin[4]arene cavities in CPOC-301, which form more multiple C–H···π hydrogen bonds with C₂H₆ than with C₂H₄ guests. This work provides a fresh avenue to utilize POC materials for highly selective separation of industrially important hydrocarbons.

A charge-separated and redox-active C ₆₀ @porous organic cage (C ₆₀ @POC) compound was synthesized to act as the cathode in a photo-assisted Li-organic battery, which enables efficient solar to electrochemical energy conversion and storage.

Although porous organic cages (POCs), particularly imine-linked (CN) ones, have advanced significantly over the last few decades, the reversible nature of imine linkages makes them prone to hydrolysis and structural collapse, severely limiting their applications under moist or water conditions. Herein, seven water-stable hydrazone-linked (CN–N) POCs are prepared through a simple coupling of the same supramolecular tetraformylresorcin[4]arene cavitand with different dihydrazide linkers. Their structures are all determined by single-crystal X-ray crystallography, demonstrating rich structural diversity from the [2 + 4] lantern, [3 + 6] triangular prism, and unprecedented [4 + 8] square prism to the extra-large [6 + 12] octahedron. In addition, they respectively exhibit tunable window diameters and cavity volumes ranging from about 5.4 to 11.1 nm and 580 to 6800 ų. Moreover, their application in the water environment for pollutant removal was explored, indicating that they can effectively eliminate various types of contaminants from water, including radionuclide waste, toxic heavy metal ions, and organic micropollutants. This work demonstrates a convenient method for rationally constructing versatile robust POCs and presents their great application potentialities in water medium.

This review aims to provide a comprehensive overview of the recent advancements made in gas separations utilizing porous organic cages (POCs).