A heterometallic polyoxometalate [Co(en)2][Co(bpy)2]2[PMoVI5MoV3VIV8O44]·4.5H2O (en = ethylenediamine, bpy = 2,2′-bipyridine) 1, has been hydrothermally synthesized, which is the first example of a two-dimensional framework where polyoxometalate anions are linked by two types of complex fragments.
18 March 2019 in Angewandte Chemie International Edition
2,2′-Biphenanthroline (2,2′-biphen) formed from 1,10-phenanthroline when a new two-dimensional layered vanadium oxide metal coordination complex, [(2,2′-biphen)Co]V3O8.5 ,which contains novel 4,8,10-net sheets, was hydrothermally synthesized.