This work reports on the synthesis of layered manganese oxides (δ-MnO₂) and their possible application as cathode intercalation materials in Al-ion and Zn-ion batteries. By using a one-pot microwave-assisted synthesis route in 1.6 M KOH (Mn_VII:Mn_II = 0.33), a pure layered δ-MnO₂ birnessite phase without any hausmannite traces was obtained after only a 14 h reaction time period at 110 °C. Attempts to enhance crystallinity level of as-prepared birnessite through increasing of reaction time up to 96 h in 1.6 M KOH failed and led to decreases in crystallinity and the emergence of an additional hausmannite phase. The influence of Mn_II:OH⁻ ratio (1:2 to 1:10) on phase crystallinity and hausmannite phase formation for 96 h reaction time was investigated as well. By increasing alkalinity of the reaction mixture up to 2.5 M KOH, a slight increase in crystallinity of birnessite phase was achieved, but hausmannite formation couldn’t be inhibited as hoped. The as-prepared layered δ-MnO₂ powder material was spray-coated on a carbon paper and tested in laboratory cells with Al or Zn as active materials. The Al-ion tests were carried out in EMIMCl/AlCl₃ while the Zn-Ion experiments were performed in water containing choline acetate (ChAcO) or a ZnSO₄ solution. Best performance in terms of capacity was yielded in the Zn-ion cell (200 mWh g⁻¹ for 20 cycles) compared to about 3 mAh g⁻¹ for the Al-ion cell. The poor activity of the latter system was attributed to low dissociation rate of tetrachloroaluminate ions (AlCl₄⁻) in the EMIMCl/AlCl₃ mixture into positive Al complexes which are needed for charge compensation of the oxide-based cathode during the discharge step.

Recently, rechargeable aluminum batteries have received much attention due to their low cost, easy operation, and high safety. As the research into rechargeable aluminum batteries with a room-temperature ionic liquid electrolyte is relatively new, research efforts have focused on finding suitable electrode materials. An understanding of the environmental aspects of electrode materials is essential to make informed and conscious decisions in aluminum battery development. The purpose of this study was to evaluate and compare the relative environmental performance of electrode material candidates for rechargeable aluminum batteries with an AlCl₃/EMIMCl (1-ethyl-3-methylimidazolium chloride) room-temperature ionic liquid electrolyte. To this end, we used a lifecycle environmental screening framework to evaluate 12 candidate electrode materials. We found that all of the studied materials are associated with one or more drawbacks and therefore do not represent a “silver bullet” for the aluminum battery. Even so, some materials appeared more promising than others did. We also found that aluminum battery technology is likely to face some of the same environmental challenges as Li-ion technology but also offers an opportunity to avoid others. The insights provided here can aid aluminum battery development in an environmentally sustainable direction.

Relatively fast and cost-effective production of porous carbon particles via a soft-template acid and base route. Impressive enhancement in Pt corrosion stability due to optimal confinement of Pt particles in mesoporous cavities of carbons.

In the present work, a 40 wt% Pt₃Cr/C alloy catalyst showed enhanced activity under both half-cell and full-cell conditions as well as excellent corrosion stability compared to those of the 40 wt% Pt/C benchmark catalyst. In half-cell experiments at 2 mA cm⁻², Pt₃Cr/C catalyst exhibited 10 mV less over-potential and twofold higher specific and mass activity for ORR than Pt/C. The average particle size grew from 4.5 nm up to “only” 6–8 nm after 7000 degradation cycles. For comparison, average particle size of Pt/C increased from 4.5 up to 10–30 nm. After 1000 degradation cycles in full-cell, MEA with Pt₃Cr/C cathode exhibits an excellent maximum power density retention of about 94% compared to only 59% for the MEA with the commercial catalyst.