The phase transition of paraffin powder mixed in wellbore concrete is generated by baking it, so that the paraffin powder is melted. The influence of baking temperature and paraffin dosage on phase transition degree of paraffin powder and the carbonation resistance of wellbore concrete was studied. Combined with microscopic testing methods such as scanning electron microscopy, the microscopic morphology of phase-transited paraffin films within the cement matrix and the mechanism by which they enhance the carbonation resistance of cement-based materials were analyzed. The results indicate that when baking temperature reaches 80 °C, the paraffin particles in the cement-based material can melt into viscous droplets. Partially melted paraffin particles condense within the internal pores of the cement matrix upon cooling, sealing the transmission pathways of CO2 gas into the cement-based material. Fully melted paraffin droplets flow within the internal pores of the cement matrix and, upon condensation, firmly adhere to the pore walls, forming a relatively dense and smooth film. This film isolates CO2 gas contact with the cement matrix, significantly improving carbonation resistance of the cement-based material. When the paraffin dosage exceeds 3% and the baking temperature surpasses 100 °C, the phase transition of paraffin powder achieves a fully carbonation-resistant effect.
Studying the additional force in topsoil containing multiple aquifers can have a significant impact on predicting shaft wall fracture and guaranteeing shaft safety, as the aquifer number increases as drainage occurs. In this study, a numerical model calculating the effect of drainage on additional force in topsoil, containing multiple aquifers, was established on the basis of several practical engineering cases. The changes in the stress displacement of the shaft wall was analyzed during three different stages of shaft construction using typical parameters, and the effects of the various factors on the additional force variation under different water level gap conditions, depending on whether the drainage was synchronized or unsynchronized, were studied. The results indicate that the increment in the additional force, with an increasing water level gap in the central aquifer, is obviously larger than that in the bottom aquifer, and the difference in the maximum additional force between these two aquifers is approximately 0.6 MPa. The increasing number of central aquifers results in a higher increment in this force, which reaches 12 MPa with an increasing number of central aquifers. Meanwhile, a threshold value (about 0.6~0.7 H) exists for the depth of a central aquifer in terms of its effect on the additional force.
Due to their advantages, artificial ground freezing methods are widely used in deep shaft construction and repair with the continuous exploitation of coal and other mineral resources. The boundary convection due to ventilation conditions will affect the formation and development of this frozen soil wall, which needs to be studied systematically. Thus, in this study, a numerical calculation model of a freezing temperature field was established based on the actual conditions of the east ventilation shaft in the Chengjiao coal mine during repair by the freezing method, and the temperature and thickness laws of the frozen soil wall and the shaft wall were studied by changing the influencing parameters. The results indicated that the thickness of the outside position gradually exceeded that of the inside position of the frozen soil wall due to the ventilation effect, and the difference between these two parameters was approximately 0.2~0.3 m, while the temperature difference was no more than 1 °C. The frozen soil wall did not complete a cross-loop within 180 d under ventilation conditions when the freezing tube pitch exceeded a certain threshold, which was about 2.3~2.5 m for this ventilation shaft. The soil moisture content played an important role in the initial freezing under ventilation conditions in the full combination calculation. This paper provides theoretical support for studying the application of the artificial ground freezing method for shaft construction and repair under ventilation conditions.
Lightweight concrete serves as an effective means of minimizing the dead load of shaft walls. In the present work, spherical lightweight aggregates produced from fly ash were employed as a substitute for conventional sand and gravel in wellbore concrete mixtures. A series of alkaline immersion curing experiments and material characterization tests were carried out to evaluate the effects of alkali type and concentration on the fundamental properties of non-sintered fly ash lightweight aggregates, including unconfined compressive strength and water resistance. The investigation also examined how aggregate grading and water-to-cement ratio influence the mechanical behavior and impermeability of fly-ash lightweight aggregate concrete. Scanning electron microscopy combined with microhardness testing was utilized to characterize the modifications in the interfacial transition zone induced by alkaline curing. A mechanistic model was proposed to explain the improvements in mechanical properties and impermeability under alkali treatment. Experimental results demonstrate that alkaline immersion promotes more complete hydration of fly ash, thereby directly enhancing both the unconfined compressive strength and impermeability of FLBA concrete. In alkali-activated FLBA concrete, the microhardness across the ITZ is considerably higher than that of the bulk cement paste matrix; the microhardness values increase as the aggregate surface is approached, and this gradient exhibits a strong correlation with the degree of improvement in mechanical strength and impermeability.
The consumption of concrete is enormous during coal mine construction in the Xinjie Taigemiao mining area. During the concrete production process, the cleaning of concrete tank trucks and mixer equipment generates a large amount of waste sludge separated from fresh concrete. How to successfully recycle waste sludge has become a key issue that urgently needs to be solved in mine construction. In this work, a method is proposed for reactivating waste sludge into cementitious materials by wet grinding to peel off hydration products from the surface of cement particles, and the influence of aging time and wet-grinding time on the mechanical properties and frost resistance of reactivated waste sludge paste are investigated; furthermore, through testing methods such as hydration heat analysis, XRD, and SEM, the hydration and hardening mechanisms of waste sludge treated by wet grinding are analyzed. The results show that wet grinding can break the adhesion between agglomerated waste particles and peel off the hydration products from the surface of the waste particles to obtain fresh cement particles, thereby restoring the cement’s hydration activity and bonding properties. The cementitious properties of reactivated waste sludge first increase and then decrease with the increase in aging time, and they first increase and then tend to stabilize with the increase in wet-grinding time; the frost resistance of the reactivated waste sludge is improved. The optimal aging time and optimal wet-grinding time for reactivated waste sludge are 14–18 h and 10 min, respectively.